Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)]
In the centrosymmetric title compound, [Ag4(C10H2O8)]n, the benzene ring has irregular bond lengths but remains planar (r.m.s. deviation 0.0002 Å). The Ag—O bond lengths are in the range 2.153 (3)–2.615 (4)&#8...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809015074 |
| _version_ | 1818791635483361280 |
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| author | Muhammad Ilyas Tariq Orhan Atakol M. Nawaz Tahir |
| author_facet | Muhammad Ilyas Tariq Orhan Atakol M. Nawaz Tahir |
| author_sort | Muhammad Ilyas Tariq |
| collection | DOAJ |
| description | In the centrosymmetric title compound, [Ag4(C10H2O8)]n, the benzene ring has irregular bond lengths but remains planar (r.m.s. deviation 0.0002 Å). The Ag—O bond lengths are in the range 2.153 (3)–2.615 (4) Å. The carboxylate groups are oriented at dihedral angles of 26.4 (5) and 74.9 (4)° to the benzene ring. The coordination behaviour of each carboxylate O atom is different: in one carboxylate, the O atoms are coordinated to a single and two Ag atoms; in the other carboxylate, the O atoms are coordinated to two and three Ag atoms. Non-classical intermolecular C—H...O hydrogen bonding is present in the crystal structure. The title compound forms a three-dimensional polymeric network due to the coordination of the Ag atoms. |
| first_indexed | 2024-12-18T15:14:29Z |
| format | Article |
| id | doaj.art-d1c4a6df78064789be23f605065b6228 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:14:29Z |
| publishDate | 2009-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d1c4a6df78064789be23f605065b62282022-12-21T21:03:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m580m58010.1107/S1600536809015074Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)]Muhammad Ilyas TariqOrhan AtakolM. Nawaz TahirIn the centrosymmetric title compound, [Ag4(C10H2O8)]n, the benzene ring has irregular bond lengths but remains planar (r.m.s. deviation 0.0002 Å). The Ag—O bond lengths are in the range 2.153 (3)–2.615 (4) Å. The carboxylate groups are oriented at dihedral angles of 26.4 (5) and 74.9 (4)° to the benzene ring. The coordination behaviour of each carboxylate O atom is different: in one carboxylate, the O atoms are coordinated to a single and two Ag atoms; in the other carboxylate, the O atoms are coordinated to two and three Ag atoms. Non-classical intermolecular C—H...O hydrogen bonding is present in the crystal structure. The title compound forms a three-dimensional polymeric network due to the coordination of the Ag atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536809015074 |
| spellingShingle | Muhammad Ilyas Tariq Orhan Atakol M. Nawaz Tahir Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)] Acta Crystallographica Section E |
| title | Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)] |
| title_full | Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)] |
| title_fullStr | Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)] |
| title_full_unstemmed | Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)] |
| title_short | Poly[(μ-benzene-1,2,4,5-tetracarboxylato)tetrasilver(I)] |
| title_sort | poly amp 956 benzene 1 2 4 5 tetracarboxylato tetrasilver i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809015074 |
| work_keys_str_mv | AT muhammadilyastariq polyamp956benzene1245tetracarboxylatotetrasilveri AT orhanatakol polyamp956benzene1245tetracarboxylatotetrasilveri AT mnawaztahir polyamp956benzene1245tetracarboxylatotetrasilveri |