Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes
In this review article different systems of dimensionally stable electrodes (DSEs) are presented with an emphasis on the application of catalytic activated titanium electrodes with a double layer platinum-group of metals (PGMs). The role of platinum metals mixed oxides (RuO2, IrO2, TiO2) as excellen...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Elsevier
2021-04-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535221001167 |
| _version_ | 1818656577230471168 |
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| author | Vesna Krstić Branka Pešovski |
| author_facet | Vesna Krstić Branka Pešovski |
| author_sort | Vesna Krstić |
| collection | DOAJ |
| description | In this review article different systems of dimensionally stable electrodes (DSEs) are presented with an emphasis on the application of catalytic activated titanium electrodes with a double layer platinum-group of metals (PGMs). The role of platinum metals mixed oxides (RuO2, IrO2, TiO2) as excellent catalysts on the surface of dimensionally stable anodes (DSAs) and a wide area of their application in various technological processes such as electrochemical engineering, wastewater treatment, degradation of pollutants, crotonaldehyde hydrogenation and fuel cells development has also been discussed. A method of forming new electrodes by using aqueous solutions of PGM chlorides which are placed on the surface of titanium substrate is also shown in this work. Very good bonding properties between the layers and the substrate contribute to the long working period of the above mentioned electrodes. One of the possible processes of surface modification of the new titanium DSAs could be the alloying of the above mentioned platinum metals on specific catalyst supports at low temperatures for the reaction of hydrogenation of crotonaldehyde. The application of DSAs could enable lower power consumption for obtaining copper and other heavy metals using electrolysis and could give cleaner deposits. On the other hand, to remove copper and other heavy metals from mining wastewater using electrolysis results in less environmental pollution. |
| first_indexed | 2024-12-17T03:27:48Z |
| format | Article |
| id | doaj.art-d1fabbe2374d4ea88f883ac4abe065ac |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-12-17T03:27:48Z |
| publishDate | 2021-04-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-d1fabbe2374d4ea88f883ac4abe065ac2022-12-21T22:05:21ZengElsevierArabian Journal of Chemistry1878-53522021-04-01144103101Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processesVesna Krstić0Branka Pešovski1Mining and Metallurgy Institute Bor, Zeleni Bulevar 35, 19210 Bor, Serbia; University of Belgrade, Technical Faculty Bor, VJ 12, 19210 Bor, Serbia; Corresponding authors.University of Belgrade, Technical Faculty Bor, VJ 12, 19210 Bor, Serbia; Corresponding authors.In this review article different systems of dimensionally stable electrodes (DSEs) are presented with an emphasis on the application of catalytic activated titanium electrodes with a double layer platinum-group of metals (PGMs). The role of platinum metals mixed oxides (RuO2, IrO2, TiO2) as excellent catalysts on the surface of dimensionally stable anodes (DSAs) and a wide area of their application in various technological processes such as electrochemical engineering, wastewater treatment, degradation of pollutants, crotonaldehyde hydrogenation and fuel cells development has also been discussed. A method of forming new electrodes by using aqueous solutions of PGM chlorides which are placed on the surface of titanium substrate is also shown in this work. Very good bonding properties between the layers and the substrate contribute to the long working period of the above mentioned electrodes. One of the possible processes of surface modification of the new titanium DSAs could be the alloying of the above mentioned platinum metals on specific catalyst supports at low temperatures for the reaction of hydrogenation of crotonaldehyde. The application of DSAs could enable lower power consumption for obtaining copper and other heavy metals using electrolysis and could give cleaner deposits. On the other hand, to remove copper and other heavy metals from mining wastewater using electrolysis results in less environmental pollution.http://www.sciencedirect.com/science/article/pii/S1878535221001167Surface modified anodeMixed metal oxide layersElectrocatalysisCrotonaldehyde hydrogenationHeterogeneous catalysisWastewater treatment |
| spellingShingle | Vesna Krstić Branka Pešovski Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes Arabian Journal of Chemistry Surface modified anode Mixed metal oxide layers Electrocatalysis Crotonaldehyde hydrogenation Heterogeneous catalysis Wastewater treatment |
| title | Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes |
| title_full | Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes |
| title_fullStr | Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes |
| title_full_unstemmed | Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes |
| title_short | Novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes |
| title_sort | novel multifunctional two layer catalytic activated titanium electrodes for various technological and environmental processes |
| topic | Surface modified anode Mixed metal oxide layers Electrocatalysis Crotonaldehyde hydrogenation Heterogeneous catalysis Wastewater treatment |
| url | http://www.sciencedirect.com/science/article/pii/S1878535221001167 |
| work_keys_str_mv | AT vesnakrstic novelmultifunctionaltwolayercatalyticactivatedtitaniumelectrodesforvarioustechnologicalandenvironmentalprocesses AT brankapesovski novelmultifunctionaltwolayercatalyticactivatedtitaniumelectrodesforvarioustechnologicalandenvironmentalprocesses |