Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar Cells

Nitroxyl radicals, characterized by unique redox properties, have been investigated for their potential influence on the photovoltaic conversion properties of dye-sensitized solar cells (DSSCs). In this study, we investigated the influence of nitroxyl radicals as donor sites in DSSCs. We observed th...

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Main Authors: Ichiro Imae, Ryosuke Akazawa, Yutaka Harima
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/17/1/77
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author Ichiro Imae
Ryosuke Akazawa
Yutaka Harima
author_facet Ichiro Imae
Ryosuke Akazawa
Yutaka Harima
author_sort Ichiro Imae
collection DOAJ
description Nitroxyl radicals, characterized by unique redox properties, have been investigated for their potential influence on the photovoltaic conversion properties of dye-sensitized solar cells (DSSCs). In this study, we investigated the influence of nitroxyl radicals as donor sites in DSSCs. We observed that the redox activity of nitroxyl radicals significantly enhanced the photovoltaic conversion efficiency of DSSCs; this finding can offer new insights into the application of these radicals in solar energy conversion. Furthermore, we found that increasing the proportion of nitroxyl radicals improved the DSSC performance. Through a combination of experimental and analytical approaches, we elucidated the mechanism underlying this enhancement and highlighted the potential for more efficient DSSCs using nitroxyl radicals as key components. These findings provide new avenues for developing advanced DSSCs with improved performances and sustainability.
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spelling doaj.art-d20b6c3340a341ae84ea40a9e637b0e72024-01-10T15:02:29ZengMDPI AGMaterials1996-19442023-12-011717710.3390/ma17010077Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar CellsIchiro Imae0Ryosuke Akazawa1Yutaka Harima2Department of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Hiroshima, JapanDepartment of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Hiroshima, JapanDepartment of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Hiroshima, JapanNitroxyl radicals, characterized by unique redox properties, have been investigated for their potential influence on the photovoltaic conversion properties of dye-sensitized solar cells (DSSCs). In this study, we investigated the influence of nitroxyl radicals as donor sites in DSSCs. We observed that the redox activity of nitroxyl radicals significantly enhanced the photovoltaic conversion efficiency of DSSCs; this finding can offer new insights into the application of these radicals in solar energy conversion. Furthermore, we found that increasing the proportion of nitroxyl radicals improved the DSSC performance. Through a combination of experimental and analytical approaches, we elucidated the mechanism underlying this enhancement and highlighted the potential for more efficient DSSCs using nitroxyl radicals as key components. These findings provide new avenues for developing advanced DSSCs with improved performances and sustainability.https://www.mdpi.com/1996-1944/17/1/77dye-sensitized solar cellsnitroxyl radicalsredox activities
spellingShingle Ichiro Imae
Ryosuke Akazawa
Yutaka Harima
Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar Cells
Materials
dye-sensitized solar cells
nitroxyl radicals
redox activities
title Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar Cells
title_full Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar Cells
title_fullStr Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar Cells
title_full_unstemmed Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar Cells
title_short Impact of Nitroxyl Radicals on Photovoltaic Conversion Properties of Dye-Sensitized Solar Cells
title_sort impact of nitroxyl radicals on photovoltaic conversion properties of dye sensitized solar cells
topic dye-sensitized solar cells
nitroxyl radicals
redox activities
url https://www.mdpi.com/1996-1944/17/1/77
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AT ryosukeakazawa impactofnitroxylradicalsonphotovoltaicconversionpropertiesofdyesensitizedsolarcells
AT yutakaharima impactofnitroxylradicalsonphotovoltaicconversionpropertiesofdyesensitizedsolarcells