An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited Miscibility
An extention of the Dabrowski and Jaroniec concept of describing adsorption from binary liquid solutions of non-electrolytes on solids in terms of the Dubinin-Radushkevich (DR) and Freundlich (F) equations is presented. A new solution has been advanced based on the definition of the chemical affinit...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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SAGE Publishing
1987-03-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/0263617487004001-209 |
| _version_ | 1826910950032146432 |
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| author | J.K. Garbacz S. Biniak P. Cysewski |
| author_facet | J.K. Garbacz S. Biniak P. Cysewski |
| author_sort | J.K. Garbacz |
| collection | DOAJ |
| description | An extention of the Dabrowski and Jaroniec concept of describing adsorption from binary liquid solutions of non-electrolytes on solids in terms of the Dubinin-Radushkevich (DR) and Freundlich (F) equations is presented. A new solution has been advanced based on the definition of the chemical affinity of the process of generation of equilibrium bulk phase from the pure components of the solution. The real adsorption isotherm equation has been formulated in which particular cases are the quasi-DR equation and the quasi-F equation. Some adsorption systems are described. |
| first_indexed | 2024-03-07T17:59:04Z |
| format | Article |
| id | doaj.art-d20bd2d6024b47bbb049f33b3cc3e950 |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2025-02-17T10:07:30Z |
| publishDate | 1987-03-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-d20bd2d6024b47bbb049f33b3cc3e9502025-01-02T02:58:54ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381987-03-01410.1177/0263617487004001-209An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited MiscibilityJ.K. Garbacz0S. Biniak1P. Cysewski2 Chemical Institute of Technology and Engineering, Technical and Agricultural University, 85-326 Bydgoszcz, Poland. Institute of Chemistry, N. Copernicus University, 87-100 Torun, Poland. Chemical Institute of Technology and Engineering, Technical and Agricultural University, 85-326 Bydgoszcz, Poland.An extention of the Dabrowski and Jaroniec concept of describing adsorption from binary liquid solutions of non-electrolytes on solids in terms of the Dubinin-Radushkevich (DR) and Freundlich (F) equations is presented. A new solution has been advanced based on the definition of the chemical affinity of the process of generation of equilibrium bulk phase from the pure components of the solution. The real adsorption isotherm equation has been formulated in which particular cases are the quasi-DR equation and the quasi-F equation. Some adsorption systems are described.https://doi.org/10.1177/0263617487004001-209 |
| spellingShingle | J.K. Garbacz S. Biniak P. Cysewski An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited Miscibility Adsorption Science & Technology |
| title | An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited Miscibility |
| title_full | An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited Miscibility |
| title_fullStr | An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited Miscibility |
| title_full_unstemmed | An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited Miscibility |
| title_short | An Attempt to Apply Analogs of the Dubinin-Radushkevich and Freundlich Equations for Describing Isotherms of Adsorption from Binary Liquid Solutions of Non-Electrolytes with Unlimited Miscibility |
| title_sort | attempt to apply analogs of the dubinin radushkevich and freundlich equations for describing isotherms of adsorption from binary liquid solutions of non electrolytes with unlimited miscibility |
| url | https://doi.org/10.1177/0263617487004001-209 |
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