Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of Mexico

A three-dimensional coupled physical–biogeochemical model was used to simulate and examine temporal and spatial variability of sea surface <i>p</i>CO<sub>2</sub> in the Gulf of Mexico (GoM). The model was driven by realistic atmospheric forcing, open boundary conditions from...

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Main Authors: Z. Xue, R. He, K. Fennel, W.-J. Cai, S. Lohrenz, W.-J. Huang, H. Tian, W. Ren, Z. Zang
Format: Article
Language:English
Published: Copernicus Publications 2016-08-01
Series:Biogeosciences
Online Access:http://www.biogeosciences.net/13/4359/2016/bg-13-4359-2016.pdf
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author Z. Xue
R. He
K. Fennel
W.-J. Cai
S. Lohrenz
W.-J. Huang
H. Tian
W. Ren
Z. Zang
author_facet Z. Xue
R. He
K. Fennel
W.-J. Cai
S. Lohrenz
W.-J. Huang
H. Tian
W. Ren
Z. Zang
author_sort Z. Xue
collection DOAJ
description A three-dimensional coupled physical–biogeochemical model was used to simulate and examine temporal and spatial variability of sea surface <i>p</i>CO<sub>2</sub> in the Gulf of Mexico (GoM). The model was driven by realistic atmospheric forcing, open boundary conditions from a data-assimilative global ocean circulation model, and observed freshwater and terrestrial nutrient and carbon input from major rivers. A 7-year model hindcast (2004–2010) was performed and validated against ship measurements. Model results revealed clear seasonality in surface <i>p</i>CO<sub>2</sub> and were used to estimate carbon budgets in the Gulf. Based on the average of model simulations, the GoM was a net CO<sub>2</sub> sink with a flux of 1.11 ± 0.84  ×  10<sup>12</sup> mol C yr<sup>−1</sup>, which, together with the enormous fluvial inorganic carbon input, was comparable to the inorganic carbon export through the Loop Current. Two model sensitivity experiments were performed: one without biological sources and sinks and the other using river input from the 1904–1910 period as simulated by the Dynamic Land Ecosystem Model (DLEM). It was found that biological uptake was the primary driver making GoM an overall CO<sub>2</sub> sink and that the carbon flux in the northern GoM was very susceptible to changes in river forcing. Large uncertainties in model simulations warrant further process-based investigations.
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spelling doaj.art-d21048d6bf1042c3823e5b3b084f5eb12022-12-21T23:56:48ZengCopernicus PublicationsBiogeosciences1726-41701726-41892016-08-0113154359437710.5194/bg-13-4359-2016Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of MexicoZ. Xue0R. He1K. Fennel2W.-J. Cai3S. Lohrenz4W.-J. Huang5H. Tian6W. Ren7Z. Zang8Department of Oceanography and Coastal Sciences, Louisiana State University, Baton Rouge, LA, USADepartment of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, NC, USADepartment of Oceanography, Dalhousie University, Halifax, CanadaSchool of Marine Science and Policy, University of Delaware, Newark, DE, USASchool for Marine Science and Technology, University of Massachusetts Dartmouth, New Bedford, MA, USADepartment of Oceanography, National Sun Yat-sen University, Kaohsiung, TaiwanSchool of Forestry and Wildlife Sciences, Auburn University, AL, USADepartment of Plant and Soil Sciences, University of Kentucky, Lexington, KY, USADepartment of Oceanography and Coastal Sciences, Louisiana State University, Baton Rouge, LA, USAA three-dimensional coupled physical–biogeochemical model was used to simulate and examine temporal and spatial variability of sea surface <i>p</i>CO<sub>2</sub> in the Gulf of Mexico (GoM). The model was driven by realistic atmospheric forcing, open boundary conditions from a data-assimilative global ocean circulation model, and observed freshwater and terrestrial nutrient and carbon input from major rivers. A 7-year model hindcast (2004–2010) was performed and validated against ship measurements. Model results revealed clear seasonality in surface <i>p</i>CO<sub>2</sub> and were used to estimate carbon budgets in the Gulf. Based on the average of model simulations, the GoM was a net CO<sub>2</sub> sink with a flux of 1.11 ± 0.84  ×  10<sup>12</sup> mol C yr<sup>−1</sup>, which, together with the enormous fluvial inorganic carbon input, was comparable to the inorganic carbon export through the Loop Current. Two model sensitivity experiments were performed: one without biological sources and sinks and the other using river input from the 1904–1910 period as simulated by the Dynamic Land Ecosystem Model (DLEM). It was found that biological uptake was the primary driver making GoM an overall CO<sub>2</sub> sink and that the carbon flux in the northern GoM was very susceptible to changes in river forcing. Large uncertainties in model simulations warrant further process-based investigations.http://www.biogeosciences.net/13/4359/2016/bg-13-4359-2016.pdf
spellingShingle Z. Xue
R. He
K. Fennel
W.-J. Cai
S. Lohrenz
W.-J. Huang
H. Tian
W. Ren
Z. Zang
Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of Mexico
Biogeosciences
title Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of Mexico
title_full Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of Mexico
title_fullStr Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of Mexico
title_full_unstemmed Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of Mexico
title_short Modeling <i>p</i>CO<sub>2</sub> variability in the Gulf of Mexico
title_sort modeling i p i co sub 2 sub variability in the gulf of mexico
url http://www.biogeosciences.net/13/4359/2016/bg-13-4359-2016.pdf
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