1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
Asymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility an...
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Format: | Article |
Language: | English |
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Beilstein-Institut
2016-05-01
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Series: | Beilstein Journal of Organic Chemistry |
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Online Access: | https://doi.org/10.3762/bjoc.12.90 |
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author | Antonia Mielgo Claudio Palomo |
author_facet | Antonia Mielgo Claudio Palomo |
author_sort | Antonia Mielgo |
collection | DOAJ |
description | Asymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility and first examples of 1H-imidazol-4(5H)-ones and thiazol-4(5H)-ones as pronucleophiles in catalytic asymmetric reactions. |
first_indexed | 2024-12-14T10:56:24Z |
format | Article |
id | doaj.art-d2135fe6d0654be0bb2a69461e016741 |
institution | Directory Open Access Journal |
issn | 1860-5397 |
language | English |
last_indexed | 2024-12-14T10:56:24Z |
publishDate | 2016-05-01 |
publisher | Beilstein-Institut |
record_format | Article |
series | Beilstein Journal of Organic Chemistry |
spelling | doaj.art-d2135fe6d0654be0bb2a69461e0167412022-12-21T23:04:54ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972016-05-0112191893610.3762/bjoc.12.901860-5397-12-901H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysisAntonia Mielgo0Claudio Palomo1Departamento de Química Orgánica I, Facultad de Química, Universidad del País Vasco, Apdo. 1072, 20080 San Sebastián, SpainDepartamento de Química Orgánica I, Facultad de Química, Universidad del País Vasco, Apdo. 1072, 20080 San Sebastián, SpainAsymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility and first examples of 1H-imidazol-4(5H)-ones and thiazol-4(5H)-ones as pronucleophiles in catalytic asymmetric reactions.https://doi.org/10.3762/bjoc.12.90asymmetric catalysisbifunctional catalysts1H-imidazol-4(5H)-onespronucleophilesthiazol-4(5H)-ones |
spellingShingle | Antonia Mielgo Claudio Palomo 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis Beilstein Journal of Organic Chemistry asymmetric catalysis bifunctional catalysts 1H-imidazol-4(5H)-ones pronucleophiles thiazol-4(5H)-ones |
title | 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis |
title_full | 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis |
title_fullStr | 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis |
title_full_unstemmed | 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis |
title_short | 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis |
title_sort | 1h imidazol 4 5h ones and thiazol 4 5h ones as emerging pronucleophiles in asymmetric catalysis |
topic | asymmetric catalysis bifunctional catalysts 1H-imidazol-4(5H)-ones pronucleophiles thiazol-4(5H)-ones |
url | https://doi.org/10.3762/bjoc.12.90 |
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