The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4)
Crystals of β-Zn3(BO3)(PO4) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title struc...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-01-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810051871 |
| _version_ | 1819105057414578176 |
|---|---|
| author | Jiyong Yao Peizhen Fu Jianxiu Zhang Sangen Zhao Erpan Zhang |
| author_facet | Jiyong Yao Peizhen Fu Jianxiu Zhang Sangen Zhao Erpan Zhang |
| author_sort | Jiyong Yao |
| collection | DOAJ |
| description | Crystals of β-Zn3(BO3)(PO4) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO3 triangles and PO4 tetrahedra, which are bridged by ZnO4 tetrahedra or ZnO5 trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed. |
| first_indexed | 2024-12-22T02:16:12Z |
| format | Article |
| id | doaj.art-d215804d5f8245d58c7d69836dc01324 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:16:12Z |
| publishDate | 2011-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d215804d5f8245d58c7d69836dc013242022-12-21T18:42:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671i3i310.1107/S1600536810051871The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4)Jiyong YaoPeizhen FuJianxiu ZhangSangen ZhaoErpan ZhangCrystals of β-Zn3(BO3)(PO4) have been grown by the Kyropoulos method. The asymmetric unit contains three Zn sites, three B-atom sites (all with symmetry 3), two P sites (both with m symmetry) and nine O-atom sites (four with m symmetry). The fundamental building units of the title structure are isolated BO3 triangles and PO4 tetrahedra, which are bridged by ZnO4 tetrahedra or ZnO5 trigonal bipyramids through common O atoms, leading to a three-dimensional framework structure. Some significant structural differences between the β-polymorph and the α-polymorph are discussed.http://scripts.iucr.org/cgi-bin/paper?S1600536810051871 |
| spellingShingle | Jiyong Yao Peizhen Fu Jianxiu Zhang Sangen Zhao Erpan Zhang The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4) Acta Crystallographica Section E |
| title | The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4) |
| title_full | The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4) |
| title_fullStr | The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4) |
| title_full_unstemmed | The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4) |
| title_short | The β-modification of trizinc borate phosphate, Zn3(BO3)(PO4) |
| title_sort | amp 946 modification of trizinc borate phosphate zn3 bo3 po4 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810051871 |
| work_keys_str_mv | AT jiyongyao theamp946modificationoftrizincboratephosphatezn3bo3po4 AT peizhenfu theamp946modificationoftrizincboratephosphatezn3bo3po4 AT jianxiuzhang theamp946modificationoftrizincboratephosphatezn3bo3po4 AT sangenzhao theamp946modificationoftrizincboratephosphatezn3bo3po4 AT erpanzhang theamp946modificationoftrizincboratephosphatezn3bo3po4 AT jiyongyao amp946modificationoftrizincboratephosphatezn3bo3po4 AT peizhenfu amp946modificationoftrizincboratephosphatezn3bo3po4 AT jianxiuzhang amp946modificationoftrizincboratephosphatezn3bo3po4 AT sangenzhao amp946modificationoftrizincboratephosphatezn3bo3po4 AT erpanzhang amp946modificationoftrizincboratephosphatezn3bo3po4 |