Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia

The Lovozero peralkaline massif (Kola Peninsula, Russia) is widely known for its unique mineral diversity, and most of the rare metal minerals are found in pegmatites, which are spatially associated with poikilitic rocks (approximately 5% of the massif volume). In order to determine the reasons for...

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Main Authors: Julia A. Mikhailova, Yakov A. Pakhomovsky, Olga F. Goychuk, Andrey O. Kalashnikov, Ayya V. Bazai, Victor N. Yakovenchuk
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/11/9/974
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author Julia A. Mikhailova
Yakov A. Pakhomovsky
Olga F. Goychuk
Andrey O. Kalashnikov
Ayya V. Bazai
Victor N. Yakovenchuk
author_facet Julia A. Mikhailova
Yakov A. Pakhomovsky
Olga F. Goychuk
Andrey O. Kalashnikov
Ayya V. Bazai
Victor N. Yakovenchuk
author_sort Julia A. Mikhailova
collection DOAJ
description The Lovozero peralkaline massif (Kola Peninsula, Russia) is widely known for its unique mineral diversity, and most of the rare metal minerals are found in pegmatites, which are spatially associated with poikilitic rocks (approximately 5% of the massif volume). In order to determine the reasons for this relationship, we have investigated petrography and the chemical composition of poikilitic rocks as well as the chemical composition of the rock-forming and accessory minerals in these rocks. The differentiation of magmatic melt during the formation of the rocks of the Lovozero massif followed the path: lujavrite → foyaite → urtite (magmatic stage) → pegmatite (hydrothermal stage). Yet, for peralkaline systems, the transition between magmatic melt and hydrothermal solution is gradual. In the case of the initially high content of volatiles in the melt, the differentiation path was probably as follows: lujavrite → foyaite (magmatic stage) → urtitization of foyaite → pegmatite (hydrothermal stage). Poikilitic rocks were formed at the stage of urtitization, and we called them pre-pegmatites. Indeed, the poikilitic rocks have a metasomatic texture and, in terms of chemical composition, correspond to magmatic urtite. The reason for the abundance of rare metal minerals in pegmatites associated with poikilitic rocks is that almost only one nepheline is deposited during urtitization, whereas during the magmatic crystallization of urtite, rare elements form accessory minerals in the rock and are less concentrated in the residual solution.
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spelling doaj.art-d217718ca63443968444fc2c04791d982023-11-22T14:21:22ZengMDPI AGMinerals2075-163X2021-09-0111997410.3390/min11090974Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, RussiaJulia A. Mikhailova0Yakov A. Pakhomovsky1Olga F. Goychuk2Andrey O. Kalashnikov3Ayya V. Bazai4Victor N. Yakovenchuk5Geological Institute of the Kola Science Centre, Russian Academy of Sciences, 14 Fersman Street, 184209 Apatity, RussiaGeological Institute of the Kola Science Centre, Russian Academy of Sciences, 14 Fersman Street, 184209 Apatity, RussiaGeological Institute of the Kola Science Centre, Russian Academy of Sciences, 14 Fersman Street, 184209 Apatity, RussiaGeological Institute of the Kola Science Centre, Russian Academy of Sciences, 14 Fersman Street, 184209 Apatity, RussiaGeological Institute of the Kola Science Centre, Russian Academy of Sciences, 14 Fersman Street, 184209 Apatity, RussiaGeological Institute of the Kola Science Centre, Russian Academy of Sciences, 14 Fersman Street, 184209 Apatity, RussiaThe Lovozero peralkaline massif (Kola Peninsula, Russia) is widely known for its unique mineral diversity, and most of the rare metal minerals are found in pegmatites, which are spatially associated with poikilitic rocks (approximately 5% of the massif volume). In order to determine the reasons for this relationship, we have investigated petrography and the chemical composition of poikilitic rocks as well as the chemical composition of the rock-forming and accessory minerals in these rocks. The differentiation of magmatic melt during the formation of the rocks of the Lovozero massif followed the path: lujavrite → foyaite → urtite (magmatic stage) → pegmatite (hydrothermal stage). Yet, for peralkaline systems, the transition between magmatic melt and hydrothermal solution is gradual. In the case of the initially high content of volatiles in the melt, the differentiation path was probably as follows: lujavrite → foyaite (magmatic stage) → urtitization of foyaite → pegmatite (hydrothermal stage). Poikilitic rocks were formed at the stage of urtitization, and we called them pre-pegmatites. Indeed, the poikilitic rocks have a metasomatic texture and, in terms of chemical composition, correspond to magmatic urtite. The reason for the abundance of rare metal minerals in pegmatites associated with poikilitic rocks is that almost only one nepheline is deposited during urtitization, whereas during the magmatic crystallization of urtite, rare elements form accessory minerals in the rock and are less concentrated in the residual solution.https://www.mdpi.com/2075-163X/11/9/974Lovozero massifperalkaline rockspegmatitesautometasomatic alteration
spellingShingle Julia A. Mikhailova
Yakov A. Pakhomovsky
Olga F. Goychuk
Andrey O. Kalashnikov
Ayya V. Bazai
Victor N. Yakovenchuk
Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia
Minerals
Lovozero massif
peralkaline rocks
pegmatites
autometasomatic alteration
title Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia
title_full Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia
title_fullStr Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia
title_full_unstemmed Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia
title_short Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia
title_sort pre pegmatite stage in peralkaline magmatic process insights from poikilitic syenites from the lovozero massif kola peninsula russia
topic Lovozero massif
peralkaline rocks
pegmatites
autometasomatic alteration
url https://www.mdpi.com/2075-163X/11/9/974
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