Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate Optimization
Cellulose ethers are biocompatible polymers which have attracted considerable attention for various applications due to their physical and mechanical properties. The present work aims to find the optimum condition for synthesizing cellulose ethers from banana blossom cellulose (BBC) such as methylce...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2024-02-01
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| Series: | Indonesian Journal of Chemistry |
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| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/86769 |
| _version_ | 1827366662838419456 |
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| author | Safira Zidna Salama Maulidan Firdaus Venty Suryanti |
| author_facet | Safira Zidna Salama Maulidan Firdaus Venty Suryanti |
| author_sort | Safira Zidna Salama |
| collection | DOAJ |
| description | Cellulose ethers are biocompatible polymers which have attracted considerable attention for various applications due to their physical and mechanical properties. The present work aims to find the optimum condition for synthesizing cellulose ethers from banana blossom cellulose (BBC) such as methylcellulose (MC), carboxymethyl cellulose (CMC) and hydroxypropyl cellulose (HPC). The ultrasonication-assisted method as an energy source is used to shorten the synthesis time at room temperature and obtain high yields. The influences of various parameters (NaOH concentration, etherification agents, and sonication time) were analyzed using a multivariate statistical modeling response surface methodology (RSM). The materials were characterized by FTIR, SEM, and TGA. The cellulose ethers obtained have the potential as food additives with DS values of 2.0, 0.7, and 0.86, respectively. MC was synthesized optimally with a yield of 96.52% using a composition of cellulose (0.4 g), 50% (w/v) NaOH (10 mL) and dichloromethane (6 mL). CMC was synthesized optimally with a yield of 98.26% using a composition of cellulose (0.4 g), 30% (w/v) NaOH (2 mL) and monochloroacetic acid (1 g). HPC was synthesized optimally with a yield of 97.51% using a composition of cellulose (0.4 g), 10% (w/v) NaOH (2 mL) and propylene oxide (1.5 mL). |
| first_indexed | 2024-03-08T08:53:50Z |
| format | Article |
| id | doaj.art-d21db61e63fd4aa6aa38723ce9d0abc8 |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-03-08T08:53:50Z |
| publishDate | 2024-02-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-d21db61e63fd4aa6aa38723ce9d0abc82024-02-01T07:39:51ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782024-02-0124120021210.22146/ijc.8676935043Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate OptimizationSafira Zidna Salama0Maulidan Firdaus1Venty Suryanti2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Surakarta 57126, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Surakarta 57126, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Surakarta 57126, IndonesiaCellulose ethers are biocompatible polymers which have attracted considerable attention for various applications due to their physical and mechanical properties. The present work aims to find the optimum condition for synthesizing cellulose ethers from banana blossom cellulose (BBC) such as methylcellulose (MC), carboxymethyl cellulose (CMC) and hydroxypropyl cellulose (HPC). The ultrasonication-assisted method as an energy source is used to shorten the synthesis time at room temperature and obtain high yields. The influences of various parameters (NaOH concentration, etherification agents, and sonication time) were analyzed using a multivariate statistical modeling response surface methodology (RSM). The materials were characterized by FTIR, SEM, and TGA. The cellulose ethers obtained have the potential as food additives with DS values of 2.0, 0.7, and 0.86, respectively. MC was synthesized optimally with a yield of 96.52% using a composition of cellulose (0.4 g), 50% (w/v) NaOH (10 mL) and dichloromethane (6 mL). CMC was synthesized optimally with a yield of 98.26% using a composition of cellulose (0.4 g), 30% (w/v) NaOH (2 mL) and monochloroacetic acid (1 g). HPC was synthesized optimally with a yield of 97.51% using a composition of cellulose (0.4 g), 10% (w/v) NaOH (2 mL) and propylene oxide (1.5 mL).https://jurnal.ugm.ac.id/ijc/article/view/86769banana blossomcelluloseetherificationresponse surface methodology |
| spellingShingle | Safira Zidna Salama Maulidan Firdaus Venty Suryanti Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate Optimization Indonesian Journal of Chemistry banana blossom cellulose etherification response surface methodology |
| title | Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate Optimization |
| title_full | Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate Optimization |
| title_fullStr | Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate Optimization |
| title_full_unstemmed | Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate Optimization |
| title_short | Cellulose Ethers from Banana (<i>Musa balbisiana</i> Colla) Blossom Cellulose: Synthesis and Multivariate Optimization |
| title_sort | cellulose ethers from banana i musa balbisiana i colla blossom cellulose synthesis and multivariate optimization |
| topic | banana blossom cellulose etherification response surface methodology |
| url | https://jurnal.ugm.ac.id/ijc/article/view/86769 |
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