Evaluation of methods for monitoring air concentrations of hydrogen sulfide

The development of different branches of industry and a growing fossil fuels mining results in a considerable emission of by-products. Major air pollutants are: CO, CO₂, SO₂, SO₃, H₂S, nitrogen oxides, as well as compounds of an organic origin. The main aspects of this paper is to review and evaluat...

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Main Authors: Katarzyna Janoszka, Agata Wziątek, Jan P. Gromiec
Format: Article
Language:English
Published: Nofer Institute of Occupational Medicine 2013-06-01
Series:Medycyna Pracy
Subjects:
Online Access:http://medpr.imp.lodz.pl/Ocena-metod-monitoringu-stezen-siarkowodoru-w-powietrzu,460,0,2.html
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author Katarzyna Janoszka
Agata Wziątek
Jan P. Gromiec
author_facet Katarzyna Janoszka
Agata Wziątek
Jan P. Gromiec
author_sort Katarzyna Janoszka
collection DOAJ
description The development of different branches of industry and a growing fossil fuels mining results in a considerable emission of by-products. Major air pollutants are: CO, CO₂, SO₂, SO₃, H₂S, nitrogen oxides, as well as compounds of an organic origin. The main aspects of this paper is to review and evaluate methods used for monitoring of hydrogen sulfide in the air. Different instrumental techniques were discussed, electrochemical, chromatographic and spectrophotometric (wet and dry), to select the method most suitable for monitoring low levels of hydrogen sulfide, close to its odor threshold. Based on the literature review the method for H₂S determination in the air, involving absorption in aqueous zinc acetate and reaction with N,N-dimethylo-p-phenylodiamine and FeCl₃, has been selected and preliminary verified. The adopted method allows for routine measurements of low concentration of hydrogen sulfide, close to its odor threshold in workplaces and ambient air. Med Pr 2013;64(3):449–454
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spelling doaj.art-d21f4843c628485c9934ab6ce9eeb6d02022-12-21T17:13:18ZengNofer Institute of Occupational MedicineMedycyna Pracy0465-58932353-13392013-06-0164344945410.13075/mp.5893.2013.0038Evaluation of methods for monitoring air concentrations of hydrogen sulfideKatarzyna JanoszkaAgata WziątekJan P. GromiecThe development of different branches of industry and a growing fossil fuels mining results in a considerable emission of by-products. Major air pollutants are: CO, CO₂, SO₂, SO₃, H₂S, nitrogen oxides, as well as compounds of an organic origin. The main aspects of this paper is to review and evaluate methods used for monitoring of hydrogen sulfide in the air. Different instrumental techniques were discussed, electrochemical, chromatographic and spectrophotometric (wet and dry), to select the method most suitable for monitoring low levels of hydrogen sulfide, close to its odor threshold. Based on the literature review the method for H₂S determination in the air, involving absorption in aqueous zinc acetate and reaction with N,N-dimethylo-p-phenylodiamine and FeCl₃, has been selected and preliminary verified. The adopted method allows for routine measurements of low concentration of hydrogen sulfide, close to its odor threshold in workplaces and ambient air. Med Pr 2013;64(3):449–454http://medpr.imp.lodz.pl/Ocena-metod-monitoringu-stezen-siarkowodoru-w-powietrzu,460,0,2.htmlhydrogen sulfidespectrophotometryair
spellingShingle Katarzyna Janoszka
Agata Wziątek
Jan P. Gromiec
Evaluation of methods for monitoring air concentrations of hydrogen sulfide
Medycyna Pracy
hydrogen sulfide
spectrophotometry
air
title Evaluation of methods for monitoring air concentrations of hydrogen sulfide
title_full Evaluation of methods for monitoring air concentrations of hydrogen sulfide
title_fullStr Evaluation of methods for monitoring air concentrations of hydrogen sulfide
title_full_unstemmed Evaluation of methods for monitoring air concentrations of hydrogen sulfide
title_short Evaluation of methods for monitoring air concentrations of hydrogen sulfide
title_sort evaluation of methods for monitoring air concentrations of hydrogen sulfide
topic hydrogen sulfide
spectrophotometry
air
url http://medpr.imp.lodz.pl/Ocena-metod-monitoringu-stezen-siarkowodoru-w-powietrzu,460,0,2.html
work_keys_str_mv AT katarzynajanoszka evaluationofmethodsformonitoringairconcentrationsofhydrogensulfide
AT agatawziatek evaluationofmethodsformonitoringairconcentrationsofhydrogensulfide
AT janpgromiec evaluationofmethodsformonitoringairconcentrationsofhydrogensulfide