Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(O...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2015-05-01
|
Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/20/5/8020 |
_version_ | 1818520435651772416 |
---|---|
author | Ioana Georgeta Grosu Christiane Berghof Peter Lönnecke Luminita Silaghi-Dumitrescu Evamarie Hey-Hawkins |
author_facet | Ioana Georgeta Grosu Christiane Berghof Peter Lönnecke Luminita Silaghi-Dumitrescu Evamarie Hey-Hawkins |
author_sort | Ioana Georgeta Grosu |
collection | DOAJ |
description | Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques. |
first_indexed | 2024-12-11T01:37:20Z |
format | Article |
id | doaj.art-d22c68fee29e487594e1d8073e763236 |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-12-11T01:37:20Z |
publishDate | 2015-05-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-d22c68fee29e487594e1d8073e7632362022-12-22T01:25:09ZengMDPI AGMolecules1420-30492015-05-012058020803210.3390/molecules20058020molecules20058020Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination PolymerIoana Georgeta Grosu0Christiane Berghof1Peter Lönnecke2Luminita Silaghi-Dumitrescu3Evamarie Hey-Hawkins4Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyInstitut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyInstitut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyDepartment of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, RomaniaInstitut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyStarting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.http://www.mdpi.com/1420-3049/20/5/80202,2'-(1,2-phenylenedisulfanediyl)diacetic acidsilver(I) complexmixed Ag-Cd coordination polymer |
spellingShingle | Ioana Georgeta Grosu Christiane Berghof Peter Lönnecke Luminita Silaghi-Dumitrescu Evamarie Hey-Hawkins Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer Molecules 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid silver(I) complex mixed Ag-Cd coordination polymer |
title | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_full | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_fullStr | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_full_unstemmed | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_short | Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer |
title_sort | silver i 2 2 1 2 phenylenedisulfanediyl diacetic acid as a molecular building block for a silver i cadmium ii coordination polymer |
topic | 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid silver(I) complex mixed Ag-Cd coordination polymer |
url | http://www.mdpi.com/1420-3049/20/5/8020 |
work_keys_str_mv | AT ioanageorgetagrosu silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer AT christianeberghof silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer AT peterlonnecke silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer AT luminitasilaghidumitrescu silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer AT evamarieheyhawkins silveri2212phenylenedisulfanediyldiaceticacidasamolecularbuildingblockforasilvericadmiumiicoordinationpolymer |