Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer

Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(O...

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Main Authors: Ioana Georgeta Grosu, Christiane Berghof, Peter Lönnecke, Luminita Silaghi-Dumitrescu, Evamarie Hey-Hawkins
Format: Article
Language:English
Published: MDPI AG 2015-05-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/20/5/8020
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author Ioana Georgeta Grosu
Christiane Berghof
Peter Lönnecke
Luminita Silaghi-Dumitrescu
Evamarie Hey-Hawkins
author_facet Ioana Georgeta Grosu
Christiane Berghof
Peter Lönnecke
Luminita Silaghi-Dumitrescu
Evamarie Hey-Hawkins
author_sort Ioana Georgeta Grosu
collection DOAJ
description Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.
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spelling doaj.art-d22c68fee29e487594e1d8073e7632362022-12-22T01:25:09ZengMDPI AGMolecules1420-30492015-05-012058020803210.3390/molecules20058020molecules20058020Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination PolymerIoana Georgeta Grosu0Christiane Berghof1Peter Lönnecke2Luminita Silaghi-Dumitrescu3Evamarie Hey-Hawkins4Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyInstitut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyInstitut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyDepartment of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, RomaniaInstitut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, GermanyStarting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.http://www.mdpi.com/1420-3049/20/5/80202,2'-(1,2-phenylenedisulfanediyl)diacetic acidsilver(I) complexmixed Ag-Cd coordination polymer
spellingShingle Ioana Georgeta Grosu
Christiane Berghof
Peter Lönnecke
Luminita Silaghi-Dumitrescu
Evamarie Hey-Hawkins
Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
Molecules
2,2'-(1,2-phenylenedisulfanediyl)diacetic acid
silver(I) complex
mixed Ag-Cd coordination polymer
title Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_full Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_fullStr Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_full_unstemmed Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_short Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer
title_sort silver i 2 2 1 2 phenylenedisulfanediyl diacetic acid as a molecular building block for a silver i cadmium ii coordination polymer
topic 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid
silver(I) complex
mixed Ag-Cd coordination polymer
url http://www.mdpi.com/1420-3049/20/5/8020
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