Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol

The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2-naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially made t...

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Main Author: Rasha KhiderHussain Al-Daffaay
Format: Article
Language:Arabic
Published: College of Science for Women, University of Baghdad 2022-10-01
Series:Baghdad Science Journal
Subjects:
Online Access:https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162
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author Rasha KhiderHussain Al-Daffaay
author_facet Rasha KhiderHussain Al-Daffaay
author_sort Rasha KhiderHussain Al-Daffaay
collection DOAJ
description The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2-naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially made to collect mono-nuclear Ni(II), Pd(II), Fe (III), and Pt(IV). (IR or FTIR), Ultraviolet Reflective (UV–visible), Mass Spectra analysis, Bohr-magnetic (B.M.), metal content, chloride content and molar conductivity have been the defining features of the composites. The Fe(III) and Pt(IV) complexes have octahedral geometries, while the Ni(II) complex has tetrahedral geometry and the Pd (II) complex has square planer geometry, according to these findings.
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spelling doaj.art-d22db5eaf8784df39e582ac348329a9d2022-12-22T02:00:55ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862022-10-0119510.21123/bsj.2022.6162Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-olRasha KhiderHussain Al-Daffaay0Department of Chemistry, College of Science, University of Baghdad, Baghdad, Iraq. The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2-naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially made to collect mono-nuclear Ni(II), Pd(II), Fe (III), and Pt(IV). (IR or FTIR), Ultraviolet Reflective (UV–visible), Mass Spectra analysis, Bohr-magnetic (B.M.), metal content, chloride content and molar conductivity have been the defining features of the composites. The Fe(III) and Pt(IV) complexes have octahedral geometries, while the Ni(II) complex has tetrahedral geometry and the Pd (II) complex has square planer geometry, according to these findings. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162Mass spectra, Metal Complexes, Schiff base
spellingShingle Rasha KhiderHussain Al-Daffaay
Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol
Baghdad Science Journal
Mass spectra, Metal Complexes, Schiff base
title Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol
title_full Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol
title_fullStr Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol
title_full_unstemmed Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol
title_short Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol
title_sort preparation and spectroscopic characterization of transition metal complexes with schiff base 2 1 1h indol 3 yl ethylimino methyl naphthalene 1 ol
topic Mass spectra, Metal Complexes, Schiff base
url https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162
work_keys_str_mv AT rashakhiderhussainaldaffaay preparationandspectroscopiccharacterizationoftransitionmetalcomplexeswithschiffbase211hindol3ylethyliminomethylnaphthalene1ol