Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol
The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2-naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially made t...
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Format: | Article |
Language: | Arabic |
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College of Science for Women, University of Baghdad
2022-10-01
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Series: | Baghdad Science Journal |
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Online Access: | https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162 |
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author | Rasha KhiderHussain Al-Daffaay |
author_facet | Rasha KhiderHussain Al-Daffaay |
author_sort | Rasha KhiderHussain Al-Daffaay |
collection | DOAJ |
description |
The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2-naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially made to collect mono-nuclear Ni(II), Pd(II), Fe (III), and Pt(IV). (IR or FTIR), Ultraviolet Reflective (UV–visible), Mass Spectra analysis, Bohr-magnetic (B.M.), metal content, chloride content and molar conductivity have been the defining features of the composites. The Fe(III) and Pt(IV) complexes have octahedral geometries, while the Ni(II) complex has tetrahedral geometry and the Pd (II) complex has square planer geometry, according to these findings.
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first_indexed | 2024-12-10T05:17:21Z |
format | Article |
id | doaj.art-d22db5eaf8784df39e582ac348329a9d |
institution | Directory Open Access Journal |
issn | 2078-8665 2411-7986 |
language | Arabic |
last_indexed | 2024-12-10T05:17:21Z |
publishDate | 2022-10-01 |
publisher | College of Science for Women, University of Baghdad |
record_format | Article |
series | Baghdad Science Journal |
spelling | doaj.art-d22db5eaf8784df39e582ac348329a9d2022-12-22T02:00:55ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862022-10-0119510.21123/bsj.2022.6162Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-olRasha KhiderHussain Al-Daffaay0Department of Chemistry, College of Science, University of Baghdad, Baghdad, Iraq. The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2-naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially made to collect mono-nuclear Ni(II), Pd(II), Fe (III), and Pt(IV). (IR or FTIR), Ultraviolet Reflective (UV–visible), Mass Spectra analysis, Bohr-magnetic (B.M.), metal content, chloride content and molar conductivity have been the defining features of the composites. The Fe(III) and Pt(IV) complexes have octahedral geometries, while the Ni(II) complex has tetrahedral geometry and the Pd (II) complex has square planer geometry, according to these findings. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162Mass spectra, Metal Complexes, Schiff base |
spellingShingle | Rasha KhiderHussain Al-Daffaay Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol Baghdad Science Journal Mass spectra, Metal Complexes, Schiff base |
title | Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol |
title_full | Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol |
title_fullStr | Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol |
title_full_unstemmed | Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol |
title_short | Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol |
title_sort | preparation and spectroscopic characterization of transition metal complexes with schiff base 2 1 1h indol 3 yl ethylimino methyl naphthalene 1 ol |
topic | Mass spectra, Metal Complexes, Schiff base |
url | https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162 |
work_keys_str_mv | AT rashakhiderhussainaldaffaay preparationandspectroscopiccharacterizationoftransitionmetalcomplexeswithschiffbase211hindol3ylethyliminomethylnaphthalene1ol |