Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives

Soluble phosphates are the most common sources currently used in crop production in tropical soils; however, they present low efficiency and are more expensive than natural rock phosphates. The objective was to develop new phosphate fertilizers with slow solubility through the partial acidification...

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Main Authors: Ana Paula Bettoni Teles, Marcos Rodrigues, Paulo Sergio Pavinato
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Agronomy
Subjects:
Online Access:https://www.mdpi.com/2073-4395/10/7/918
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author Ana Paula Bettoni Teles
Marcos Rodrigues
Paulo Sergio Pavinato
author_facet Ana Paula Bettoni Teles
Marcos Rodrigues
Paulo Sergio Pavinato
author_sort Ana Paula Bettoni Teles
collection DOAJ
description Soluble phosphates are the most common sources currently used in crop production in tropical soils; however, they present low efficiency and are more expensive than natural rock phosphates. The objective was to develop new phosphate fertilizers with slow solubility through the partial acidification of rock phosphates (RPs), incorporating materials with adsorption characteristics to favor slow dissolution and prevent phosphorus (P) fixation in the soil. Three rock phosphates, Araxá (ARP), Bayovar (BRP) and Morocco (MRP), were evaluated at two acidulation levels (25 and 50% Ac.) and two additives; pillared clays (PILC) and zeolites (Zeo), plus triple superphosphate (TSP) and a control (nil-P). The soil diffusion was evaluated in concentric rings in Petri dishes. Solubility was evaluated in leaching columns and sampled in layers from surface for P forms in the soil profile. The relative agronomic efficiency (RAE) was evaluated in maize. Greater diffusion was provided by TSP, followed by BRP and MRP both with 50% Ac. + Zeo, and MRP with 50% Ac. + PILC. Percolated P was more pronounced under TSP, followed by RPs (BRP and MRP) with 50% Ac. + Zeo. BRP and MRP + 50% Ac. were the most promising sources with RAE above 74% compared to TSP.
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spelling doaj.art-d2450283d977413982d286ba440aafe42023-11-20T05:06:32ZengMDPI AGAgronomy2073-43952020-06-0110791810.3390/agronomy10070918Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as AdditivesAna Paula Bettoni Teles0Marcos Rodrigues1Paulo Sergio Pavinato2College of Agriculture Luiz de Queiroz—ESALQ-USP, Av. Pádua Dias, 11, Piracicaba-SP 13418-900, BrazilCollege of Agriculture Luiz de Queiroz—ESALQ-USP, Av. Pádua Dias, 11, Piracicaba-SP 13418-900, BrazilCollege of Agriculture Luiz de Queiroz—ESALQ-USP, Av. Pádua Dias, 11, Piracicaba-SP 13418-900, BrazilSoluble phosphates are the most common sources currently used in crop production in tropical soils; however, they present low efficiency and are more expensive than natural rock phosphates. The objective was to develop new phosphate fertilizers with slow solubility through the partial acidification of rock phosphates (RPs), incorporating materials with adsorption characteristics to favor slow dissolution and prevent phosphorus (P) fixation in the soil. Three rock phosphates, Araxá (ARP), Bayovar (BRP) and Morocco (MRP), were evaluated at two acidulation levels (25 and 50% Ac.) and two additives; pillared clays (PILC) and zeolites (Zeo), plus triple superphosphate (TSP) and a control (nil-P). The soil diffusion was evaluated in concentric rings in Petri dishes. Solubility was evaluated in leaching columns and sampled in layers from surface for P forms in the soil profile. The relative agronomic efficiency (RAE) was evaluated in maize. Greater diffusion was provided by TSP, followed by BRP and MRP both with 50% Ac. + Zeo, and MRP with 50% Ac. + PILC. Percolated P was more pronounced under TSP, followed by RPs (BRP and MRP) with 50% Ac. + Zeo. BRP and MRP + 50% Ac. were the most promising sources with RAE above 74% compared to TSP.https://www.mdpi.com/2073-4395/10/7/918phosphorus sourcesP solubilizationP acidulationrelative agronomic efficiency
spellingShingle Ana Paula Bettoni Teles
Marcos Rodrigues
Paulo Sergio Pavinato
Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives
Agronomy
phosphorus sources
P solubilization
P acidulation
relative agronomic efficiency
title Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives
title_full Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives
title_fullStr Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives
title_full_unstemmed Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives
title_short Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives
title_sort solubility and efficiency of rock phosphate fertilizers partially acidulated with zeolite and pillared clay as additives
topic phosphorus sources
P solubilization
P acidulation
relative agronomic efficiency
url https://www.mdpi.com/2073-4395/10/7/918
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