Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide
In the title salt, C10H11N4O2+·I−, the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 ...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015001541 |
| _version_ | 1818914336407552000 |
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| author | Roumaissa Belguedj Abdelmalek Bouraiou Hocine Merazig Ali Belfaitah Sofiane Bouacida |
| author_facet | Roumaissa Belguedj Abdelmalek Bouraiou Hocine Merazig Ali Belfaitah Sofiane Bouacida |
| author_sort | Roumaissa Belguedj |
| collection | DOAJ |
| description | In the title salt, C10H11N4O2+·I−, the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 (6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The structure features two types of hydrogen bonds (C—H...O and C—H...I), viz. cation–anion and cation–cation, which lead to the form ation of a three-dimensional network. |
| first_indexed | 2024-12-19T23:44:46Z |
| format | Article |
| id | doaj.art-d24c38f5cdde40e5b5228ac005792075 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-19T23:44:46Z |
| publishDate | 2015-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-d24c38f5cdde40e5b5228ac0057920752022-12-21T20:01:20ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-01712o133o13410.1107/S2056989015001541hg5425Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodideRoumaissa Belguedj0Abdelmalek Bouraiou1Hocine Merazig2Ali Belfaitah3Sofiane Bouacida4Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine1, 25000 , AlgeriaUnité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine1, 25000 , AlgeriaUnité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine1, 25000 , AlgeriaEquipe de Synthèse de Molécules à Objectif Thérapeutique, Laboratoire des Produits Naturels d'Origine Végétale et de Synthèse Organique, Université Constantine 1, Constantine 25000, AlgeriaUnité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine1, 25000 , AlgeriaIn the title salt, C10H11N4O2+·I−, the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 (6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The structure features two types of hydrogen bonds (C—H...O and C—H...I), viz. cation–anion and cation–cation, which lead to the form ation of a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2056989015001541crystal structureimidazolepyridiniumiodidehydrogen bonding |
| spellingShingle | Roumaissa Belguedj Abdelmalek Bouraiou Hocine Merazig Ali Belfaitah Sofiane Bouacida Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide Acta Crystallographica Section E: Crystallographic Communications crystal structure imidazole pyridinium iodide hydrogen bonding |
| title | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
| title_full | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
| title_fullStr | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
| title_full_unstemmed | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
| title_short | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
| title_sort | crystal structure of 1 1 methyl 5 nitro 1h imidazol 2 yl methyl pyridinium iodide |
| topic | crystal structure imidazole pyridinium iodide hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015001541 |
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