Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvate
In the title compound, [Zn(C7H7N2O4)2(H2O)2]·2C3H7NO, the ZnII ion, which lies on a center of inversion, is coordinated by two O atoms and two N atoms from two 4-carboxy-2-ethyl-1H-imidazole-5-carboxylato anions and two water O atoms in an octahedral environment, Each 4-carboxy-2-ethyl-...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-05-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811012992 |
| _version_ | 1798030817931296768 |
|---|---|
| author | Cheng-Jun Hao Hui Xie |
| author_facet | Cheng-Jun Hao Hui Xie |
| author_sort | Cheng-Jun Hao |
| collection | DOAJ |
| description | In the title compound, [Zn(C7H7N2O4)2(H2O)2]·2C3H7NO, the ZnII ion, which lies on a center of inversion, is coordinated by two O atoms and two N atoms from two 4-carboxy-2-ethyl-1H-imidazole-5-carboxylato anions and two water O atoms in an octahedral environment, Each 4-carboxy-2-ethyl-1H-imidazole-5-carboxylato ligand adopts a bidentate chelating mode to the ZnII ion, forming two five-membered metalla rings. In the crystal, a two-dimensional framework parallel to (010) is formed by N—H...O and O—H...O hydrogen bonds. |
| first_indexed | 2024-04-11T19:47:32Z |
| format | Article |
| id | doaj.art-d2548b41bd624238871d4b4e98f301dc |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:47:32Z |
| publishDate | 2011-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d2548b41bd624238871d4b4e98f301dc2022-12-22T04:06:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675m583m58310.1107/S1600536811012992Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvateCheng-Jun HaoHui XieIn the title compound, [Zn(C7H7N2O4)2(H2O)2]·2C3H7NO, the ZnII ion, which lies on a center of inversion, is coordinated by two O atoms and two N atoms from two 4-carboxy-2-ethyl-1H-imidazole-5-carboxylato anions and two water O atoms in an octahedral environment, Each 4-carboxy-2-ethyl-1H-imidazole-5-carboxylato ligand adopts a bidentate chelating mode to the ZnII ion, forming two five-membered metalla rings. In the crystal, a two-dimensional framework parallel to (010) is formed by N—H...O and O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811012992 |
| spellingShingle | Cheng-Jun Hao Hui Xie Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvate Acta Crystallographica Section E |
| title | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvate |
| title_full | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvate |
| title_fullStr | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvate |
| title_full_unstemmed | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvate |
| title_short | Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)zinc N,N-dimethylformamide disolvate |
| title_sort | diaquabis 4 carboxy 2 ethyl 1h imidazole 5 carboxylato amp 954 2n3 o4 zinc n n dimethylformamide disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811012992 |
| work_keys_str_mv | AT chengjunhao diaquabis4carboxy2ethyl1himidazole5carboxylatoamp9542n3o4zincnndimethylformamidedisolvate AT huixie diaquabis4carboxy2ethyl1himidazole5carboxylatoamp9542n3o4zincnndimethylformamidedisolvate |