4-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenol
In the title compound, C29H23ClN2O, the 5-chlorophenol ring and the imidazole ring are nearly coplanar, with a dihedral angle of 15.76 (9)° between them. The ethylphenyl ring and the two phenyl rings subtend angles of 71.09 (7), 43.95 (5) and 36.53 (9)°, respectively, with the imidazole plane. An i...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2020-01-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619016900 |
| _version_ | 1818613110475325440 |
|---|---|
| author | K. N. Shraddha S. Devika Noor Shahina Begum |
| author_facet | K. N. Shraddha S. Devika Noor Shahina Begum |
| author_sort | K. N. Shraddha |
| collection | DOAJ |
| description | In the title compound, C29H23ClN2O, the 5-chlorophenol ring and the imidazole ring are nearly coplanar, with a dihedral angle of 15.76 (9)° between them. The ethylphenyl ring and the two phenyl rings subtend angles of 71.09 (7), 43.95 (5) and 36.53 (9)°, respectively, with the imidazole plane. An intramolecular O—H...N hydrogen bond supports the molecular conformation, and an intermolecular C—H...O interaction, originating from an ortho-phenyl H atom, stabilizes the packing arrangement. In addition, a weak C—H...π interaction, also involving an ortho-phenyl H atom, is observed. |
| first_indexed | 2024-12-16T15:56:54Z |
| format | Article |
| id | doaj.art-d26f9aa7a2f9411db4cc97970b6527c5 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-16T15:56:54Z |
| publishDate | 2020-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-d26f9aa7a2f9411db4cc97970b6527c52022-12-21T22:25:34ZengInternational Union of CrystallographyIUCrData2414-31462020-01-0151x19169010.1107/S2414314619016900zl40374-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenolK. N. Shraddha0S. Devika1Noor Shahina Begum2Department of Studies in Chemistry, Bangalore University, Jnana Bharathi Campus, Bangalore 560 056, Karnataka, IndiaDepartment of Studies in Chemistry, Bangalore University, Jnana Bharathi Campus, Bangalore 560 056, Karnataka, IndiaDepartment of Studies in Chemistry, Bangalore University, Jnana Bharathi Campus, Bangalore 560 056, Karnataka, IndiaIn the title compound, C29H23ClN2O, the 5-chlorophenol ring and the imidazole ring are nearly coplanar, with a dihedral angle of 15.76 (9)° between them. The ethylphenyl ring and the two phenyl rings subtend angles of 71.09 (7), 43.95 (5) and 36.53 (9)°, respectively, with the imidazole plane. An intramolecular O—H...N hydrogen bond supports the molecular conformation, and an intermolecular C—H...O interaction, originating from an ortho-phenyl H atom, stabilizes the packing arrangement. In addition, a weak C—H...π interaction, also involving an ortho-phenyl H atom, is observed.http://scripts.iucr.org/cgi-bin/paper?S2414314619016900crystal structureimidazolehydrogen bonding |
| spellingShingle | K. N. Shraddha S. Devika Noor Shahina Begum 4-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenol IUCrData crystal structure imidazole hydrogen bonding |
| title | 4-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenol |
| title_full | 4-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenol |
| title_fullStr | 4-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenol |
| title_full_unstemmed | 4-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenol |
| title_short | 4-Chloro-2-[1-(4-ethylphenyl)-4,5-diphenyl-1H-imidazol-2-yl]phenol |
| title_sort | 4 chloro 2 1 4 ethylphenyl 4 5 diphenyl 1h imidazol 2 yl phenol |
| topic | crystal structure imidazole hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619016900 |
| work_keys_str_mv | AT knshraddha 4chloro214ethylphenyl45diphenyl1himidazol2ylphenol AT sdevika 4chloro214ethylphenyl45diphenyl1himidazol2ylphenol AT noorshahinabegum 4chloro214ethylphenyl45diphenyl1himidazol2ylphenol |