A review of the adsorption method for norfloxacin reduction from aqueous media
Norfloxacin (NRFX) is one of a class of antibiotics known as broad-spectrum fluoroquinolone antibiotic that is frequently used to treat infectious disorders in both animals and humans. NRFX is considered an emergent pharmaceutical contaminate. This review's objective is to evaluate empirical da...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2023-01-01
|
| Series: | MethodsX |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2215016123001802 |
| _version_ | 1827917811258753024 |
|---|---|
| author | Paschal Enyinnaya Ohale Chinenye Adaobi Igwegbe Kingsley O. Iwuozor Ebuka Chizitere Emenike Christopher Chiedozie Obi Andrzej Białowiec |
| author_facet | Paschal Enyinnaya Ohale Chinenye Adaobi Igwegbe Kingsley O. Iwuozor Ebuka Chizitere Emenike Christopher Chiedozie Obi Andrzej Białowiec |
| author_sort | Paschal Enyinnaya Ohale |
| collection | DOAJ |
| description | Norfloxacin (NRFX) is one of a class of antibiotics known as broad-spectrum fluoroquinolone antibiotic that is frequently used to treat infectious disorders in both animals and humans. NRFX is considered an emergent pharmaceutical contaminate. This review's objective is to evaluate empirical data on NRFX's removal from aqueous medium. The environmental danger of NRFX in the aquatic environment was validated by an initial ecotoxicological study. Graphene oxide/Metal Organic Framework (MOF) based composite, followed by Magnesium oxide/Chitosan/Graphene oxide composite gave the highest NRFX adsorption capacities (Qmax) of 1114.8 and 1000 mg/g, respectively. The main adsorption mechanisms for NRFX uptake include electrostatic interactions, H-bonds, π–π interactions, electron donor-acceptor interactions, hydrophobic interactions, and pore diffusion. The adsorptive uptake of NRFX were most suitably described by Langmuir isotherm and pseudo-second order implying adsorbate-to-adsorbent electron transfer on a monolayer surface. The thermodynamics of NRFX uptake is heavily dependent on the makeup of the adsorbent, and the selection of the eluent for desorption from the solid phase is equally important. There were detected knowledge gaps in column studies and adsorbent disposal method. There's great interest in scale-up and industrial applications of research results that will aid in management of water resources for sustainability. |
| first_indexed | 2024-03-13T03:32:49Z |
| format | Article |
| id | doaj.art-d270d40ed5ef42cc96e0d07c031b79ff |
| institution | Directory Open Access Journal |
| issn | 2215-0161 |
| language | English |
| last_indexed | 2024-03-13T03:32:49Z |
| publishDate | 2023-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | MethodsX |
| spelling | doaj.art-d270d40ed5ef42cc96e0d07c031b79ff2023-06-24T05:17:38ZengElsevierMethodsX2215-01612023-01-0110102180A review of the adsorption method for norfloxacin reduction from aqueous mediaPaschal Enyinnaya Ohale0Chinenye Adaobi Igwegbe1Kingsley O. Iwuozor2Ebuka Chizitere Emenike3Christopher Chiedozie Obi4Andrzej Białowiec5Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, NigeriaDepartment of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria; Department of Applied Bioeconomy, Wroclaw University of Environmental and Life Sciences, Poland; Corresponding authors.Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria; Nigeria Sugar Institute, Ilorin, Nigeria; Corresponding authors.Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, P. M. B. 5025, Awka, NigeriaDepartment of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria; Department of Polymer Engineering, Nnamdi Azikiwe University, P.M.B. 5025, Awka 420218, NigeriaDepartment of Applied Bioeconomy, Wroclaw University of Environmental and Life Sciences, PolandNorfloxacin (NRFX) is one of a class of antibiotics known as broad-spectrum fluoroquinolone antibiotic that is frequently used to treat infectious disorders in both animals and humans. NRFX is considered an emergent pharmaceutical contaminate. This review's objective is to evaluate empirical data on NRFX's removal from aqueous medium. The environmental danger of NRFX in the aquatic environment was validated by an initial ecotoxicological study. Graphene oxide/Metal Organic Framework (MOF) based composite, followed by Magnesium oxide/Chitosan/Graphene oxide composite gave the highest NRFX adsorption capacities (Qmax) of 1114.8 and 1000 mg/g, respectively. The main adsorption mechanisms for NRFX uptake include electrostatic interactions, H-bonds, π–π interactions, electron donor-acceptor interactions, hydrophobic interactions, and pore diffusion. The adsorptive uptake of NRFX were most suitably described by Langmuir isotherm and pseudo-second order implying adsorbate-to-adsorbent electron transfer on a monolayer surface. The thermodynamics of NRFX uptake is heavily dependent on the makeup of the adsorbent, and the selection of the eluent for desorption from the solid phase is equally important. There were detected knowledge gaps in column studies and adsorbent disposal method. There's great interest in scale-up and industrial applications of research results that will aid in management of water resources for sustainability.http://www.sciencedirect.com/science/article/pii/S2215016123001802A review of the adsorption method for norfloxacin reduction from aqueous media |
| spellingShingle | Paschal Enyinnaya Ohale Chinenye Adaobi Igwegbe Kingsley O. Iwuozor Ebuka Chizitere Emenike Christopher Chiedozie Obi Andrzej Białowiec A review of the adsorption method for norfloxacin reduction from aqueous media MethodsX A review of the adsorption method for norfloxacin reduction from aqueous media |
| title | A review of the adsorption method for norfloxacin reduction from aqueous media |
| title_full | A review of the adsorption method for norfloxacin reduction from aqueous media |
| title_fullStr | A review of the adsorption method for norfloxacin reduction from aqueous media |
| title_full_unstemmed | A review of the adsorption method for norfloxacin reduction from aqueous media |
| title_short | A review of the adsorption method for norfloxacin reduction from aqueous media |
| title_sort | review of the adsorption method for norfloxacin reduction from aqueous media |
| topic | A review of the adsorption method for norfloxacin reduction from aqueous media |
| url | http://www.sciencedirect.com/science/article/pii/S2215016123001802 |
| work_keys_str_mv | AT paschalenyinnayaohale areviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT chinenyeadaobiigwegbe areviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT kingsleyoiwuozor areviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT ebukachizitereemenike areviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT christopherchiedozieobi areviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT andrzejbiałowiec areviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT paschalenyinnayaohale reviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT chinenyeadaobiigwegbe reviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT kingsleyoiwuozor reviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT ebukachizitereemenike reviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT christopherchiedozieobi reviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia AT andrzejbiałowiec reviewoftheadsorptionmethodfornorfloxacinreductionfromaqueousmedia |