Resonant X-ray photo-oxidation of light-harvesting iron (II/III) N-heterocyclic carbene complexes

Resonant X-ray photo-oxidation of light-harvesting iron (II/III) N-heterocyclic carbene complexes

Abstract Two photoactive iron N-heterocyclic carbene complexes $${[\hbox {Fe}^{{{\rm{II}}}}(\hbox {btz})_2(\hbox {bpy})]^{2+}}$$ [ Fe II ( btz ) 2 ( bpy ) ] 2 + and $${[\hbox {Fe}^{{\rm{III}}}(\hbox {btz})_3]^{3+}}$$ [ Fe III ( btz ) 3 ] 3 + , where btz is 3,3’-dimethyl-1,1’-bis(p-tolyl)-4,4’-bis(1,...

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Main Authors: Robert H. Temperton, Meiyuan Guo, Giulio D’Acunto, Niclas Johansson, Nils W. Rosemann, Om Prakash, Kenneth Wärnmark, Joachim Schnadt, Jens Uhlig, Petter Persson
Format: Article
Language:English
Published: Nature Portfolio 2021-11-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-021-01509-7

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