Phosphazene Functionalized Silsesquioxane-Based Porous Polymer as Thermally Stable and Reusable Catalyst for Bulk Ring-Opening Polymerization of ε-Caprolactone

Phosphazene Functionalized Silsesquioxane-Based Porous Polymer as Thermally Stable and Reusable Catalyst for Bulk Ring-Opening Polymerization of ε-Caprolactone

The bulk ring-opening polymerization (ROP) of ε-caprolactone using phosphazene-containing porous polymeric material (HPCP) has been studied at high reaction temperatures (130–150 °C). HPCP in conjunction with benzyl alcohol as an initiator induced the living ROP of ε-caprolactone, affording polyeste...

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Bibliographic Details
Main Authors:	Yuliya A. Piskun, Evgenii A. Ksendzov, Anastasiya V. Resko, Mikhail A. Soldatov, Peter Timashev, Hongzhi Liu, Irina V. Vasilenko, Sergei V. Kostjuk
Format:	Article
Language:	English
Published:	MDPI AG 2023-03-01
Series:	Polymers
Subjects:	ring-opening polymerization phosphazene base ε-caprolactone porous polymeric material heterogeneous catalysis
Online Access:	https://www.mdpi.com/2073-4360/15/5/1291

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