Decolorization of industrial wastewater using electrochemical peroxidation process

In this study, decolorization of wastewater samples taken from the paper industry is investigated using electrochemical peroxidation process. The electrochemical peroxidation process is a part of electrochemical advanced oxidation processes, which is based on the Fenton’s chemical reaction, provided...

Full description

Bibliographic Details
Main Authors: Elin Marlina, Purwanto Purwanto, Sudarno Sudarno
Format: Article
Language:English
Published: International Association of Physical Chemists (IAPC) 2021-12-01
Series:Journal of Electrochemical Science and Engineering
Subjects:
Online Access:https://pub.iapchem.org/ojs/index.php/JESE/article/view/1017
_version_ 1819349698175041536
author Elin Marlina
Purwanto Purwanto
Sudarno Sudarno
author_facet Elin Marlina
Purwanto Purwanto
Sudarno Sudarno
author_sort Elin Marlina
collection DOAJ
description In this study, decolorization of wastewater samples taken from the paper industry is investigated using electrochemical peroxidation process. The electrochemical peroxidation process is a part of electrochemical advanced oxidation processes, which is based on the Fenton’s chemical reaction, provided by addition of external H2O2 into reaction cell. In this study, iron is used as anode and graphite as cathode put at the fixed distance of 30 mm in a glass reaction cell. The cell was filled with the solution containing wastewater and sodium chloride as the supporting electrolyte. Factors of the process such as pH, current intensity, hydrogen peroxide concentration, and time of treatment were studied. The results illustrate that all these parameters affect efficiencies of dye removal and chemical oxygen demand (COD) reducing. The maximal removal of wastewater contaminants was achieved under acid (pH 3) condition, with the applied current of 1 A, and hydrogen peroxide concentration of 0.033 M. At these conditions, decolorization process efficiency reached 100 and 83 % of COD removal after 40 minutes of wastewater sample treatment. In addition, the electrical energy consumption for wastewater treatment by electrochemical peroxidation is calculated, showing increase as the current intensity of treatment process was increased. The obtained results suggest that electrochemical peroxidation process can be used for removing dye compounds and chemical oxygen demand (COD) from industrial wastewaters with high removal efficiency.
first_indexed 2024-12-24T19:04:39Z
format Article
id doaj.art-d28823bc1b09427ab59138b131ccea7a
institution Directory Open Access Journal
issn 1847-9286
language English
last_indexed 2024-12-24T19:04:39Z
publishDate 2021-12-01
publisher International Association of Physical Chemists (IAPC)
record_format Article
series Journal of Electrochemical Science and Engineering
spelling doaj.art-d28823bc1b09427ab59138b131ccea7a2022-12-21T16:43:08ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862021-12-0111310.5599/jese.1017Decolorization of industrial wastewater using electrochemical peroxidation processElin Marlina0Purwanto Purwanto1Sudarno Sudarno2Doctoral Program of Environmental Science, School of Postgraduate Studies, Universitas Diponegoro, Semarang, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Semarang, IndonesiaDepartment of Environmental Engineering, Faculty of Engineering, Universitas Diponegoro, Semarang, IndonesiaIn this study, decolorization of wastewater samples taken from the paper industry is investigated using electrochemical peroxidation process. The electrochemical peroxidation process is a part of electrochemical advanced oxidation processes, which is based on the Fenton’s chemical reaction, provided by addition of external H2O2 into reaction cell. In this study, iron is used as anode and graphite as cathode put at the fixed distance of 30 mm in a glass reaction cell. The cell was filled with the solution containing wastewater and sodium chloride as the supporting electrolyte. Factors of the process such as pH, current intensity, hydrogen peroxide concentration, and time of treatment were studied. The results illustrate that all these parameters affect efficiencies of dye removal and chemical oxygen demand (COD) reducing. The maximal removal of wastewater contaminants was achieved under acid (pH 3) condition, with the applied current of 1 A, and hydrogen peroxide concentration of 0.033 M. At these conditions, decolorization process efficiency reached 100 and 83 % of COD removal after 40 minutes of wastewater sample treatment. In addition, the electrical energy consumption for wastewater treatment by electrochemical peroxidation is calculated, showing increase as the current intensity of treatment process was increased. The obtained results suggest that electrochemical peroxidation process can be used for removing dye compounds and chemical oxygen demand (COD) from industrial wastewaters with high removal efficiency.https://pub.iapchem.org/ojs/index.php/JESE/article/view/1017Paper industry wastewaterelectrochemical peroxidationFenton’s reactiondecolori¬zation efficiencychemical oxygen demand
spellingShingle Elin Marlina
Purwanto Purwanto
Sudarno Sudarno
Decolorization of industrial wastewater using electrochemical peroxidation process
Journal of Electrochemical Science and Engineering
Paper industry wastewater
electrochemical peroxidation
Fenton’s reaction
decolori¬zation efficiency
chemical oxygen demand
title Decolorization of industrial wastewater using electrochemical peroxidation process
title_full Decolorization of industrial wastewater using electrochemical peroxidation process
title_fullStr Decolorization of industrial wastewater using electrochemical peroxidation process
title_full_unstemmed Decolorization of industrial wastewater using electrochemical peroxidation process
title_short Decolorization of industrial wastewater using electrochemical peroxidation process
title_sort decolorization of industrial wastewater using electrochemical peroxidation process
topic Paper industry wastewater
electrochemical peroxidation
Fenton’s reaction
decolori¬zation efficiency
chemical oxygen demand
url https://pub.iapchem.org/ojs/index.php/JESE/article/view/1017
work_keys_str_mv AT elinmarlina decolorizationofindustrialwastewaterusingelectrochemicalperoxidationprocess
AT purwantopurwanto decolorizationofindustrialwastewaterusingelectrochemicalperoxidationprocess
AT sudarnosudarno decolorizationofindustrialwastewaterusingelectrochemicalperoxidationprocess