Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation

This study aimed to optimize the removal of Cu(II) ions from an aqueous solution using a <i>Jatropha</i> oil bio-based membrane blended with 0.50 wt% graphene oxide (JPU/GO 0.50 wt%) using a central composite model (CCD) design using response surface methodology. The input factors were t...

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Main Authors: Nur Haninah Harun, Zurina Zainal Abidin, Umar Adam Majid, Mohamad Rezi Abdul Hamid, Abdul Halim Abdullah, Rizafizah Othaman, Mohd Yusof Harun
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/16/3325
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author Nur Haninah Harun
Zurina Zainal Abidin
Umar Adam Majid
Mohamad Rezi Abdul Hamid
Abdul Halim Abdullah
Rizafizah Othaman
Mohd Yusof Harun
author_facet Nur Haninah Harun
Zurina Zainal Abidin
Umar Adam Majid
Mohamad Rezi Abdul Hamid
Abdul Halim Abdullah
Rizafizah Othaman
Mohd Yusof Harun
author_sort Nur Haninah Harun
collection DOAJ
description This study aimed to optimize the removal of Cu(II) ions from an aqueous solution using a <i>Jatropha</i> oil bio-based membrane blended with 0.50 wt% graphene oxide (JPU/GO 0.50 wt%) using a central composite model (CCD) design using response surface methodology. The input factors were the feed concentration (60–140) ppm, pressure (1.5–2.5) bar, and solution pH value (3–5). An optimum Cu(II) ions removal of 87% was predicted at 116 ppm feed concentration, 1.5 bar pressure, and pH 3.7, while the validated experimental result recorded 80% Cu(II) ions removal, with 95% of prediction intervals. A statistically non-significant term was removed from the analysis by the backward elimination method to improve the model’s accuracy. Using the reduction method, the predicted R<sup>2</sup> value was increased from −0.16 (−16%) to 0.88 (88%), suggesting that the reduced model had a good predictive ability. The quadratic regression model was significant (R<sup>2</sup> = 0.98) for the optimization prediction. Therefore, the results from the reduction model implied acceptable membrane performance, offering a better process optimization for Cu(II) ions removal.
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spelling doaj.art-d2c3510fafce46c4b220cc5f391705e22023-12-02T00:11:57ZengMDPI AGPolymers2073-43602022-08-011416332510.3390/polym14163325Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental RemediationNur Haninah Harun0Zurina Zainal Abidin1Umar Adam Majid2Mohamad Rezi Abdul Hamid3Abdul Halim Abdullah4Rizafizah Othaman5Mohd Yusof Harun6Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, MalaysiaDepartment of Chemical Science and Food Technology, Universiti Kebangsaan Malaysia, Bangi 43600, MalaysiaDepartment of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang 43400, MalaysiaThis study aimed to optimize the removal of Cu(II) ions from an aqueous solution using a <i>Jatropha</i> oil bio-based membrane blended with 0.50 wt% graphene oxide (JPU/GO 0.50 wt%) using a central composite model (CCD) design using response surface methodology. The input factors were the feed concentration (60–140) ppm, pressure (1.5–2.5) bar, and solution pH value (3–5). An optimum Cu(II) ions removal of 87% was predicted at 116 ppm feed concentration, 1.5 bar pressure, and pH 3.7, while the validated experimental result recorded 80% Cu(II) ions removal, with 95% of prediction intervals. A statistically non-significant term was removed from the analysis by the backward elimination method to improve the model’s accuracy. Using the reduction method, the predicted R<sup>2</sup> value was increased from −0.16 (−16%) to 0.88 (88%), suggesting that the reduced model had a good predictive ability. The quadratic regression model was significant (R<sup>2</sup> = 0.98) for the optimization prediction. Therefore, the results from the reduction model implied acceptable membrane performance, offering a better process optimization for Cu(II) ions removal.https://www.mdpi.com/2073-4360/14/16/3325membranefiltrationrenewablebiodegradablesustainable<i>Jatropha</i>
spellingShingle Nur Haninah Harun
Zurina Zainal Abidin
Umar Adam Majid
Mohamad Rezi Abdul Hamid
Abdul Halim Abdullah
Rizafizah Othaman
Mohd Yusof Harun
Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
Polymers
membrane
filtration
renewable
biodegradable
sustainable
<i>Jatropha</i>
title Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_full Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_fullStr Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_full_unstemmed Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_short Adopting Sustainable <i>Jatropha</i> Oil Bio-Based Polymer Membranes as Alternatives for Environmental Remediation
title_sort adopting sustainable i jatropha i oil bio based polymer membranes as alternatives for environmental remediation
topic membrane
filtration
renewable
biodegradable
sustainable
<i>Jatropha</i>
url https://www.mdpi.com/2073-4360/14/16/3325
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