N′-(2-Hydroxy-5-chlorobenzylidene)-4-nitrobenzohydrazide methanol solvate

The title compound, C14H10ClN3O4·CH4O, was synthesized from the reaction of 5-chlorosalicylaldehyde with 4-nitrobenzohydrazide in methanol. The Schiff base molecule is nearly planar, with a dihedral angle of 9.1 (3)° between the two benzene rings. The methanol solvent mol...

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Bibliographic Details
Main Authors: Yun-Peng Diao, Xue-Mei Zhou, Qing-Bai Huang, Shan-Shan Huang, Ling Han
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680800843X
Description
Summary:The title compound, C14H10ClN3O4·CH4O, was synthesized from the reaction of 5-chlorosalicylaldehyde with 4-nitrobenzohydrazide in methanol. The Schiff base molecule is nearly planar, with a dihedral angle of 9.1 (3)° between the two benzene rings. The methanol solvent molecules are linked to the Schiff base molecules by N—H...O, O—H...N and O—H...O hydrogen bonds, forming chains running parallel to the a axis.
ISSN:1600-5368