New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions

A very simple method based on electrical conductivity and pH measurements was proposed for assessing reactivity of pozzolans. Calcium hydroxide:pozzolan water suspensions were monitored by means of measurements of electrical conductivity and pH values. In these suspensions, Ca(OH)2 in solid state wa...

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Main Authors: M. M. Tashima, L. Soriano, J. Monzó, M. V. Borrachero, J. L. Akasaki, J. Payá
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Científicas 2014-12-01
Series:Materiales de Construccion
Subjects:
Online Access:http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/1563
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author M. M. Tashima
L. Soriano
J. Monzó
M. V. Borrachero
J. L. Akasaki
J. Payá
author_facet M. M. Tashima
L. Soriano
J. Monzó
M. V. Borrachero
J. L. Akasaki
J. Payá
author_sort M. M. Tashima
collection DOAJ
description A very simple method based on electrical conductivity and pH measurements was proposed for assessing reactivity of pozzolans. Calcium hydroxide:pozzolan water suspensions were monitored by means of measurements of electrical conductivity and pH values. In these suspensions, Ca(OH)2 in solid state was initially present, being them, thus, saturated in this reagent. Three testing temperatures were selected (40, 50 and 60 °C). In the experiments carried out, calcium hydroxide was suspended in deionized water for yielding a lime saturated suspension. The addition of siliceous pozzolan (two types of rice husk ash RHA and two types of densified silica fume DSF were tested) to the saturated lime suspension can produce the unsaturation of the system, depending on the testing time, testing temperature and reactivity of pozzolan. When unsaturation was reached, the loss of electrical conductivity was higher than 30% and the variation of pH was higher than 0.15 units. These threshold values were selected for characterizing the reactivity of pozzolans by means of a proposed template, classifying the pozzolan in three different reactivity levels.
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spelling doaj.art-d2da7d746c254933af133f7f7391090a2022-12-21T17:13:54ZengConsejo Superior de Investigaciones CientíficasMateriales de Construccion0465-27461988-32262014-12-0164316e032e03210.3989/mc.2014.009141508New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensionsM. M. Tashima0L. Soriano1J. Monzó2M. V. Borrachero3J. L. Akasaki4J. Payá5UNESP – Univ Estadual PaulistaUniversitat Politècnica de ValènciaUniversitat Politècnica de ValènciaUniversitat Politècnica de ValènciaUNESP – Univ Estadual PaulistaUniversitat Politècnica de ValènciaA very simple method based on electrical conductivity and pH measurements was proposed for assessing reactivity of pozzolans. Calcium hydroxide:pozzolan water suspensions were monitored by means of measurements of electrical conductivity and pH values. In these suspensions, Ca(OH)2 in solid state was initially present, being them, thus, saturated in this reagent. Three testing temperatures were selected (40, 50 and 60 °C). In the experiments carried out, calcium hydroxide was suspended in deionized water for yielding a lime saturated suspension. The addition of siliceous pozzolan (two types of rice husk ash RHA and two types of densified silica fume DSF were tested) to the saturated lime suspension can produce the unsaturation of the system, depending on the testing time, testing temperature and reactivity of pozzolan. When unsaturation was reached, the loss of electrical conductivity was higher than 30% and the variation of pH was higher than 0.15 units. These threshold values were selected for characterizing the reactivity of pozzolans by means of a proposed template, classifying the pozzolan in three different reactivity levels.http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/1563reactioncharacterizationsiliceous pozzolansilica fumerice husk ash
spellingShingle M. M. Tashima
L. Soriano
J. Monzó
M. V. Borrachero
J. L. Akasaki
J. Payá
New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions
Materiales de Construccion
reaction
characterization
siliceous pozzolan
silica fume
rice husk ash
title New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions
title_full New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions
title_fullStr New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions
title_full_unstemmed New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions
title_short New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions
title_sort new method to assess the pozzolanic reactivity of mineral admixtures by means of ph and electrical conductivity measurements in lime pozzolan suspensions
topic reaction
characterization
siliceous pozzolan
silica fume
rice husk ash
url http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/1563
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