Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca Alloys

The microstructures and mechanical properties of Mg–3Sn–0.1Ca–xMM (mischmetal, x = 0.3, 0.6, and 0.9 wt.%) alloys were investigated. Optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction spectroscopy (XRD) were used to characterize the microstructures and phase constituti...

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Main Authors: Jun Luo, Lijun Dong, Guowei Zhong, Zhenxing Duan, Shuang Chen, Anru Wu
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/9/1379
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author Jun Luo
Lijun Dong
Guowei Zhong
Zhenxing Duan
Shuang Chen
Anru Wu
author_facet Jun Luo
Lijun Dong
Guowei Zhong
Zhenxing Duan
Shuang Chen
Anru Wu
author_sort Jun Luo
collection DOAJ
description The microstructures and mechanical properties of Mg–3Sn–0.1Ca–xMM (mischmetal, x = 0.3, 0.6, and 0.9 wt.%) alloys were investigated. Optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction spectroscopy (XRD) were used to characterize the microstructures and phase constitutions of the cast and rolled alloys. Room temperature tensile tests were conducted to obtain the mechanical properties and macro-textures to evaluate the texture weakening effect results of the MM. The results show that an abundance of second phase formed, confirmed as the (Ca,MM)MgSn phase, and the volume fraction increased with the increasing MM addition. The tensile yield strength of the as-cast alloys increased with the MM addition, but the elongation decreased. All of the rolled Mg–3Sn–0.1Ca–xMM alloys showed a strong basal texture, and only slightly decreased in intensity after annealing treatment due to the particle-stimulated nucleation of recrystallization. The as-annealed Mg–3Sn–0.1Ca–0.6MM alloys exhibited the highest tensile strengths of 266.5 ± 3.3 MPa and 136.1 ± 3.7 MPa, which are mainly ascribed to grain refinement strengthening, Orowan strengthening and texture strengthening.
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spelling doaj.art-d2dbcba9931e42228e80d508ef6b79002023-11-19T10:09:51ZengMDPI AGCrystals2073-43522023-09-01139137910.3390/cryst13091379Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca AlloysJun Luo0Lijun Dong1Guowei Zhong2Zhenxing Duan3Shuang Chen4Anru Wu5Hunan Provincial Key Laboratory of Vehicle Power and Transmission System, Hunan Institute of Engineering, Xiangtan 411104, ChinaHunan Provincial Key Laboratory of Vehicle Power and Transmission System, Hunan Institute of Engineering, Xiangtan 411104, ChinaSchool of Mechanical Engineering, Hunan Institute of Engineering, Xiangtan 411104, ChinaSchool of Mechanical Engineering, Hunan Institute of Engineering, Xiangtan 411104, ChinaHunan Provincial Key Laboratory of Vehicle Power and Transmission System, Hunan Institute of Engineering, Xiangtan 411104, ChinaHunan Provincial Key Laboratory of Vehicle Power and Transmission System, Hunan Institute of Engineering, Xiangtan 411104, ChinaThe microstructures and mechanical properties of Mg–3Sn–0.1Ca–xMM (mischmetal, x = 0.3, 0.6, and 0.9 wt.%) alloys were investigated. Optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction spectroscopy (XRD) were used to characterize the microstructures and phase constitutions of the cast and rolled alloys. Room temperature tensile tests were conducted to obtain the mechanical properties and macro-textures to evaluate the texture weakening effect results of the MM. The results show that an abundance of second phase formed, confirmed as the (Ca,MM)MgSn phase, and the volume fraction increased with the increasing MM addition. The tensile yield strength of the as-cast alloys increased with the MM addition, but the elongation decreased. All of the rolled Mg–3Sn–0.1Ca–xMM alloys showed a strong basal texture, and only slightly decreased in intensity after annealing treatment due to the particle-stimulated nucleation of recrystallization. The as-annealed Mg–3Sn–0.1Ca–0.6MM alloys exhibited the highest tensile strengths of 266.5 ± 3.3 MPa and 136.1 ± 3.7 MPa, which are mainly ascribed to grain refinement strengthening, Orowan strengthening and texture strengthening.https://www.mdpi.com/2073-4352/13/9/1379Mg–Sn alloysmischmetalmicrostructuretexturemechanical properties
spellingShingle Jun Luo
Lijun Dong
Guowei Zhong
Zhenxing Duan
Shuang Chen
Anru Wu
Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca Alloys
Crystals
Mg–Sn alloys
mischmetal
microstructure
texture
mechanical properties
title Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca Alloys
title_full Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca Alloys
title_fullStr Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca Alloys
title_full_unstemmed Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca Alloys
title_short Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg–Sn–Ca Alloys
title_sort effect of mischmetal addition on microstructure and mechanical properties of as cast and as rolled mg sn ca alloys
topic Mg–Sn alloys
mischmetal
microstructure
texture
mechanical properties
url https://www.mdpi.com/2073-4352/13/9/1379
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