(<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamide
(<i>R</i>)-(+)-3,5-dinitro-<i>N</i>-(1-phenylethyl)benzothioamide <b>1</b> is a potential chiral solvating agent (CSA) for the spectral resolution of enantiomers via <sup>1</sup>H NMR spectroscopy. The single enantiomer of <b>1</b> was synt...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-05-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2023/2/M1650 |
| _version_ | 1797593340857810944 |
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| author | Matthew G. Donahue Emily Crull |
| author_facet | Matthew G. Donahue Emily Crull |
| author_sort | Matthew G. Donahue |
| collection | DOAJ |
| description | (<i>R</i>)-(+)-3,5-dinitro-<i>N</i>-(1-phenylethyl)benzothioamide <b>1</b> is a potential chiral solvating agent (CSA) for the spectral resolution of enantiomers via <sup>1</sup>H NMR spectroscopy. The single enantiomer of <b>1</b> was synthesized from commercially available (<i>R</i>)-(+)-a-methylbenzylamine <b>2</b> in two steps with 85% yield. |
| first_indexed | 2024-03-11T02:07:44Z |
| format | Article |
| id | doaj.art-d2f1b4c044c3482c980bbaec6afe5f33 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-11T02:07:44Z |
| publishDate | 2023-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-d2f1b4c044c3482c980bbaec6afe5f332023-11-18T11:47:04ZengMDPI AGMolbank1422-85992023-05-0120232M165010.3390/M1650(<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamideMatthew G. Donahue0Emily Crull1Department of Chemistry and Biochemistry, University of Southern Mississippi, Hattiesburg, MS 39406, USADepartment of Chemistry and Biochemistry, University of Southern Mississippi, Hattiesburg, MS 39406, USA(<i>R</i>)-(+)-3,5-dinitro-<i>N</i>-(1-phenylethyl)benzothioamide <b>1</b> is a potential chiral solvating agent (CSA) for the spectral resolution of enantiomers via <sup>1</sup>H NMR spectroscopy. The single enantiomer of <b>1</b> was synthesized from commercially available (<i>R</i>)-(+)-a-methylbenzylamine <b>2</b> in two steps with 85% yield.https://www.mdpi.com/1422-8599/2023/2/M1650benzylaminechiral solvating agentthioamide |
| spellingShingle | Matthew G. Donahue Emily Crull (<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamide Molbank benzylamine chiral solvating agent thioamide |
| title | (<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamide |
| title_full | (<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamide |
| title_fullStr | (<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamide |
| title_full_unstemmed | (<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamide |
| title_short | (<i>R</i>)-(+)-3,5-Dinitro-<i>N</i>-(1-phenylethyl)benzothioamide |
| title_sort | i r i 3 5 dinitro i n i 1 phenylethyl benzothioamide |
| topic | benzylamine chiral solvating agent thioamide |
| url | https://www.mdpi.com/1422-8599/2023/2/M1650 |
| work_keys_str_mv | AT matthewgdonahue iri35dinitroini1phenylethylbenzothioamide AT emilycrull iri35dinitroini1phenylethylbenzothioamide |