Electronic interactions in [Ru3(m3-R2 CCC6H4-4-R1)(m -dppm)(m-CO) (CO)7] (R1 = NO2 and R2 = Fc; R1 = NO2, CN and R2 = Ph)

Electronic interactions in [Ru3(m3-R2 CCC6H4-4-R1)(m -dppm)(m-CO) (CO)7] (R1 = NO2 and R2 = Fc; R1 = NO2, CN and R2 = Ph)

The co-ordination of FcCCC6H4-4-NO2 (1) to a ruthenium carbonyl cluster to yield [Ru3(mu 3-FcCCC6H4-4-NO2) (mu-dppm)( mu-CO)(CO)7] (2) is reported. The cyclic voltammograms of these compounds and of the analogous clusters [Ru3(mu3 -eta2-C6 H5CCC6H4-4-R)(mu -dppm)(mu -CO)(CO)7] (R= H, 3; CN, 4; NO2,...

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Bibliographic Details
Main Authors: Rosseto Renato, Torres José C., Stein Edison, Vargas Maria D.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2003-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
ruthenium cluster
ferrocene
alkyne
cyclic voltammetry
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000100002

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000100002

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