Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled Plasmas

Although pulse-modulated plasma has overcome various problems encountered during the development of the high aspect ratio contact hole etching process, there is still a lack of understanding in terms of precisely how the pulse-modulated plasma solves the issues. In this research, to gain insight int...

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Main Authors: Chulhee Cho, Kwangho You, Sijun Kim, Youngseok Lee, Jangjae Lee, Shinjae You
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/17/5036
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author Chulhee Cho
Kwangho You
Sijun Kim
Youngseok Lee
Jangjae Lee
Shinjae You
author_facet Chulhee Cho
Kwangho You
Sijun Kim
Youngseok Lee
Jangjae Lee
Shinjae You
author_sort Chulhee Cho
collection DOAJ
description Although pulse-modulated plasma has overcome various problems encountered during the development of the high aspect ratio contact hole etching process, there is still a lack of understanding in terms of precisely how the pulse-modulated plasma solves the issues. In this research, to gain insight into previously observed phenomena, SiO<sub>2</sub> etching characteristics were investigated under various pulsed plasma conditions and analyzed through plasma diagnostics. Specifically, the disappearance of micro-trenching from the use of pulse-modulated plasma is analyzed via self-bias, and the phenomenon that as power off-time increases, the sidewall angle increases is interpreted via radical species density and self-bias. Further, the change from etching to deposition with decreased peak power during processing is understood via self-bias and electron density. It is expected that this research will provide an informative window for the optimization of SiO<sub>2</sub> etching and for basic processing databases including plasma diagnosis for advanced plasma processing simulators.
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spelling doaj.art-d3287647585846abb09f60d1776ad9402023-11-22T10:55:20ZengMDPI AGMaterials1996-19442021-09-011417503610.3390/ma14175036Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled PlasmasChulhee Cho0Kwangho You1Sijun Kim2Youngseok Lee3Jangjae Lee4Shinjae You5Department of Physics, Chungnam National University, 99 Daehak-ro, Daejeon 34134, KoreaDepartment of Physics, Chungnam National University, 99 Daehak-ro, Daejeon 34134, KoreaNanotech, Yongin 28431, KoreaDepartment of Physics, Chungnam National University, 99 Daehak-ro, Daejeon 34134, KoreaDepartment of Physics, Chungnam National University, 99 Daehak-ro, Daejeon 34134, KoreaDepartment of Physics, Chungnam National University, 99 Daehak-ro, Daejeon 34134, KoreaAlthough pulse-modulated plasma has overcome various problems encountered during the development of the high aspect ratio contact hole etching process, there is still a lack of understanding in terms of precisely how the pulse-modulated plasma solves the issues. In this research, to gain insight into previously observed phenomena, SiO<sub>2</sub> etching characteristics were investigated under various pulsed plasma conditions and analyzed through plasma diagnostics. Specifically, the disappearance of micro-trenching from the use of pulse-modulated plasma is analyzed via self-bias, and the phenomenon that as power off-time increases, the sidewall angle increases is interpreted via radical species density and self-bias. Further, the change from etching to deposition with decreased peak power during processing is understood via self-bias and electron density. It is expected that this research will provide an informative window for the optimization of SiO<sub>2</sub> etching and for basic processing databases including plasma diagnosis for advanced plasma processing simulators.https://www.mdpi.com/1996-1944/14/17/5036silicon dioxide etchingliquid fluorocarbon precursorglobal warming potential (GWP)etch selectivitycapacitively coupled plasmapulse-modulated plasma
spellingShingle Chulhee Cho
Kwangho You
Sijun Kim
Youngseok Lee
Jangjae Lee
Shinjae You
Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled Plasmas
Materials
silicon dioxide etching
liquid fluorocarbon precursor
global warming potential (GWP)
etch selectivity
capacitively coupled plasma
pulse-modulated plasma
title Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled Plasmas
title_full Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled Plasmas
title_fullStr Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled Plasmas
title_full_unstemmed Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled Plasmas
title_short Characterization of SiO<sub>2</sub> Etching Profiles in Pulse-Modulated Capacitively Coupled Plasmas
title_sort characterization of sio sub 2 sub etching profiles in pulse modulated capacitively coupled plasmas
topic silicon dioxide etching
liquid fluorocarbon precursor
global warming potential (GWP)
etch selectivity
capacitively coupled plasma
pulse-modulated plasma
url https://www.mdpi.com/1996-1944/14/17/5036
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AT sijunkim characterizationofsiosub2subetchingprofilesinpulsemodulatedcapacitivelycoupledplasmas
AT youngseoklee characterizationofsiosub2subetchingprofilesinpulsemodulatedcapacitivelycoupledplasmas
AT jangjaelee characterizationofsiosub2subetchingprofilesinpulsemodulatedcapacitivelycoupledplasmas
AT shinjaeyou characterizationofsiosub2subetchingprofilesinpulsemodulatedcapacitivelycoupledplasmas