(6R,7R)-3-Hydroxymethyl-7-(2-phenylacetamido)-3-cephem-4-carboxylic acid lactone

(6R,7R)-3-Hydroxymethyl-7-(2-phenylacetamido)-3-cephem-4-carboxylic acid lactone

In the title compound {systematic name: N-[(4R,5R)-3,11-dioxo-10-oxa-6-thia-2-azatricyclo[6.3.0.02,5]undec-1(8)-en-4-yl]-2-phenylacetamide}, C16H14N2O4S, the four- and five-membered rings adopt planar conformations (with r.m.s. deviations of 0.0349 and 0.0108&#8197;&#197; respectivel...

Full description

Bibliographic Details
Main Authors:	Xiao-Liang Zhou, Hao Wang, Yan Wang, Pei-Ji Shi
Format:	Article
Language:	English
Published:	International Union of Crystallography 2011-11-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536811043881

Similar Items

ISOLATION FROM CASTANOSPERMUM-AUSTRALE AND X-RAY CRYSTAL-STRUCTURE OF 3,8-DIEPIALEXINE, (1R,2R,3S,7S,8R)-3-HYDROXYMETHYL-1,2,7-TRIHYDROXYPYRROLIZIDINE [(2S,3R,4R,5S,6R)-2-HYDROXYMETHYL-1-AZABICYCLO[3.3.0]OCTAN-3,4,6-TRIOL]
by: Nash, R, et al.
Published: (1988)

SYNTHESIS FROM D-GLUCOSE OF ALEXINE [(1R,2R,3R,7S,8S)-3-HYDROXYMETHYL-1,2,7-TRIHYDROXYPYRROLIZIDINE], 3-EPIALEXINE AND 7-EPIALEXINE
by: Fleet, G, et al.
Published: (1988)

Synthesis of three branched iminosugars [(3R,4R,5S)-3-(hydroxymethyl)piperidine-3,4,5-triol, (3R,4R,5R)-3-(hydroxymethyl)piperidine-3,4,5-triol and (3S,4R,5R)-3-(hydroxymethyl)piperidine-3.4,5-triol] and a branched trihydroxynipecotic acid [(3R,4R,5R)-3,4,5-trihydroxypiperidine-3-carboxylic acid] from sugar lactones with a carbon substituent at C-2
by: Simone, M, et al.
Published: (2012)

ISOLATION FROM ALEXA-LEIOPETALA AND X-RAY CRYSTAL-STRUCTURE OF ALEXINE, (1R,2R,3R,7S,8S)-3-HYDROXYMETHYL-1,2,7-TRIHYDROXYPYRROLIZIDINE [(2R,3R,4R,5S,6S)-2-HYDROXYMETHYL-1-AZABICYCLO[3.3.0]OCTAN-3,4,6-TRIOL], A UNIQUE PYRROLIZIDINE ALKALOID
by: Nash, R, et al.
Published: (1988)

First diastereoselective total synthesis of bicyclic styryl lactone: (1R,5R,7R)-7-((E)-styryl)-2,6-dioxabicyclo[3.3.1]nonan-3-one
by: Dhanraj O. Biradar, et al.
Published: (2023-01-01)

(2R*,6S*)-tert-Butyl 2,6-bis(hydroxymethyl)morpholine-4-carboxylate
by: Qian Chen, et al.
Published: (2010-07-01)

(2R,3R)-2-[(4-Chlorophenyl)hydroxymethyl]cyclopentanone
by: Dongsheng Deng, et al.
Published: (2009-01-01)

Crystal structure of (3aR,5S,6R,6aR)-6-hydroxy-5-hydroxymethyl-perhydrofuro[3,2-b]furan-2-one, C7H10O5
by: Frey W., et al.
Published: (1999-06-01)

(2R,3S,4R,5R)-5-(4-Amino-5-iodo-7H-pyrrolo[2,3-d]pyrimidin-7-yl)-4-fluoro-2-(hydroxymethyl)tetrahydrofuran-3-ol
by: Wei Li, et al.
Published: (2014-02-01)

SYNTHESIS OF CIS-1-AMINO-3-HYDROXYMETHYL-CYCLOBUTANE-1-CARBOXYLIC AND TRANS-1-AMINO-3-HYDROXYMETHYL-CYCLOBUTANE-1-CARBOXYLIC ACIDS
by: Fleet, G, et al.
Published: (1988)

2-Chloro-3-hydroxymethyl-7,8-dimethylquinoline
by: Khan, F.N., et al.
Published: (2010)

2-Chloro-3-hydroxymethyl-7,8-dimethylquinoline
by: F. Nawaz Khan, et al.
Published: (2010-01-01)

(1R,3S)-Methyl 6,7-dimethoxy-1-(4-methoxyphenyl)-1,2,3,4-tetrahydroisoquinoline-3-carboxylate
by: Glenn E. M. Maguire, et al.
Published: (2010-12-01)

Crystal structure of 3S,4S,5R,6S,7R-5-amino-6-(tert-butyldimethylsiloxy)-7- (tert-butyldimethylsiloxymethyl)-3-hydroxymethyl-2,2-dimethyloxepan-4-ol, C22H49NO5Si2
by: AI-Hanasi A., et al.
Published: (2006-04-01)

Crystal structure of (2S,3S,4aR,6aS,7aR,7bR)-methyl 2,3-dimethoxy- 2,3-dimethyl-3,4a,6a,7,7a,7b-hexahydro-2H-cyclopropa[ 3,4]benzo-[1,2-b]dioxine-6-carboxylate, C15H22O6
by: Frey Wolfgang, et al.
Published: (2011-12-01)

(3aR*,6S*,7S*,7aR*)-2-(4-Methoxybenzyl)-7-(4-nitrophenyl)-6-phenyl-3a,6,7,7a-tetrahydroisoindolin-1-one
by: Jian Zhao, et al.
Published: (2010-06-01)

(3aR,6S,7aR)-7a-Chloro-6-methyl-2-(4-nitrophenylsulfonyl)-1,2,3,6,7,7a-hexahydro-3a,6-epoxyisoindole
by: Aydın Demircan, et al.
Published: (2013-11-01)

(3aR,6S,7aR)-7a-Bromo-2-[(4-methylphenyl)sulfonyl]-1,2,3,6,7,7a-hexahydro-3a,6-epoxyisoindole
by: Ba&#351;ak Ko&#351;ar, et al.
Published: (2011-04-01)

(3aR,6S,7aR)-7a-Chloro-2-[(4-nitrophenyl)sulfonyl]-1,2,3,6,7,7a-hexahydro-3a,6-epoxyisoindole
by: Ersin Temel, et al.
Published: (2013-10-01)

Crystal structure of ethyl (3aR,4R,5R,6R,7aR)-4,5-diacetoxy-6-acetoxymethyl- 2-oxy-3a,5,6,7a-tetrahydro-4H-pyrano[3,2-d]isoxazole-3-carboxylate, C16H21NO11
by: Peters K., et al.
Published: (2005-04-01)

Crystal structure of (1S,3R,4R,5S,6R)-4-0-benzyl-4.5-dihydroxy-3-hydroxymethyl- 2,7-dioxabicyclo-[4.3.0]nonan-8-on, C15H18O6
by: Henkel S., et al.
Published: (1997-12-01)

Crystal structure of (1S,3R,4R,5S,6R)-4-0-benzyl-4.5-dihydroxy-3-hydroxymethyl- 2,7-dioxabicyclo-[4.3.0]nonan-8-on, C15H18O6
by: Henkel S., et al.
Published: (1997-12-01)

(1R,3S)-Methyl 2-benzyl-6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate
by: Glenn E. M. Maguire, et al.
Published: (2009-12-01)

2-azido-(R)-3,5-O-benzylidene-2-deoxy-2-C-methyl-D-xylono-1,4-lactone [(2S, 4aR, 7R,7aR)-7-azido-7-methyl-2-phenyldihydro-4H-furo[3,2-d][1,3]dioxin6(4aH)-one]
by: Hotchkiss, D, et al.
Published: (2007)

(1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
by: Mohamed Loubidi, et al.
Published: (2014-05-01)

(3aR*,6S*,7aR*)-7a-Chloro-6-methyl-2-(4-methylphenylsulfonyl)-2,3,3a,6,7,7a-hexahydro-3a,6-epoxy-1H-isoindole
by: Ersin Temel, et al.
Published: (2012-04-01)

A Corey lactone: crystal structure of (3aR,4R,5R,6aS)-5-benzoyloxy-4(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one, C15H16O5
by: Wang Kun-Yan, et al.
Published: (2018-01-01)

5-(Hydroxymethyl)furan-2-carboxylic acid
by: Jun-Liang Liu, et al.
Published: (2011-06-01)

(1S,3S,8R,10R,11R)-3,7,7,10-Tetramethyltricyclo[6.4.0.01,3]dodecan-11-ol
by: Moha Berraho, et al.
Published: (2013-08-01)

(3R,4S,5R,6R,7S)-3,4,5,7-Tetrahydroxyconidine, an azetidine analogue of 6,7-diepicastanospermine and a conformationally constrained d-deoxyaltronojirimycin, from l-arabinose.
by: Martínez, R, et al.
Published: (2013)

Crystal structure of tert-butyl (1S,2R,5R)-2-(hydroxymethyl)-4-(4-methoxyphenyl)-6-oxa-3-azabicyclo[3.1.0]hexane-3-carboxylate, C17H23NO5
by: Caracelli Ignez, et al.
Published: (2020-10-01)

A concise synthesis of (5R,6S)-tert-butyl 5-acetoxy-6-(hydroxymethyl)-5,6-dihydropyridine-1(2H)-carboxylate
by: S. Ramalingam, et al.
Published: (2012-10-01)

(1R,3S)-3-Hydroxymethyl-N-isopropyl-2,2-dimethylcyclopropanecarboxamide
by: Jiangchun Zhong, et al.
Published: (2010-01-01)

5,6,7,8-Tetrahydronaphthalene-1-carboxylic acid
by: Ya-Ling Liu, et al.
Published: (2009-12-01)

7-Hydroxy-4-(hydroxymethyl)coumarin
by: Jun-Hua Bai, et al.
Published: (2016-04-01)

Crystal structure of (3R,4S)-6,8-dihydroxy-3,4,5-trimethyl-1- oxoisochroman-7-carboxylic acid, C13H14O6
by: Chang Hong, et al.
Published: (2009-09-01)

[6-(Hydroxymethyl)pyridin-2-yl]methyl ferrocene-1-carboxylate
by: Mathieu Auzias, et al.
Published: (2011-11-01)

(1S,3R,8R,9R,10S)-2,2-Dibromo-3,7,7,10-tetramethyl-9β,10β-epoxy-3,7,7,10-tetramethyltricyclo[6.4.0.01,3]dodecane
by: Abdelouahd Oukhrib, et al.
Published: (2013-04-01)

Crystal structure of (3R,4S)-6,8-dihydroxy-3,4,5-trimethyl-1-oxoisochroman- 7-carboxylic acid, C13H14O6
by: Chang1 Hong, et al.
Published: (2009-04-01)

Crystal structure of (3S*,4S*,4aS*,5R*,6R*,6aS*,7R*,11aS*,11bR*)-5,6-bis(benzoyloxy)-3,4a-dihydroxy-4,7,11b-trimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-4-carboxylic acid methanol monosolvate
by: Sadaf Siddiqui, et al.
Published: (2015-10-01)