An efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode
Abstract In this proposed work, direct green 6 (DG6) decorated carbon paste electrode (CPE) was fabricated for the efficient simultaneous and individual sensing of catechol (CA) and hydroquinone (HY). Electrochemical deeds of the CA and HY were carried out by cyclic voltammetry (CV) and differential...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2021-07-01
|
| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-021-93749-w |
| _version_ | 1818834668512870400 |
|---|---|
| author | K. Chetankumar B. E. Kumara Swamy S. C. Sharma S. A. Hariprasad |
| author_facet | K. Chetankumar B. E. Kumara Swamy S. C. Sharma S. A. Hariprasad |
| author_sort | K. Chetankumar |
| collection | DOAJ |
| description | Abstract In this proposed work, direct green 6 (DG6) decorated carbon paste electrode (CPE) was fabricated for the efficient simultaneous and individual sensing of catechol (CA) and hydroquinone (HY). Electrochemical deeds of the CA and HY were carried out by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) at poly-DG6-modfied carbon paste electrode (Po-DG6-MCPE). Using scanning electron microscopy (SEM) studied the surface property of unmodified CPE (UCPE) and Po-DG6-MCPE. The decorated sensor displayed admirable electrocatalytic performance with fine stability, reproducibility, selectivity, low limit of detection (LLOD) for HY (0.11 μM) and CC (0.09 μM) and sensor process was originated to be adsorption-controlled phenomena. The Po-DG6-MCPE sensor exhibits well separated two peaks for HY and CA in CV and DPV analysis with potential difference of 0.098 V. Subsequently, the sensor was practically applied for the analysis in tap water and it consistent in-between for CA 93.25–100.16% and for HY 97.25–99.87% respectively. |
| first_indexed | 2024-12-19T02:38:29Z |
| format | Article |
| id | doaj.art-d34a40b5afd246dba5248fcc22c84261 |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-12-19T02:38:29Z |
| publishDate | 2021-07-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-d34a40b5afd246dba5248fcc22c842612022-12-21T20:39:15ZengNature PortfolioScientific Reports2045-23222021-07-0111111310.1038/s41598-021-93749-wAn efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrodeK. Chetankumar0B. E. Kumara Swamy1S. C. Sharma2S. A. Hariprasad3Department of P.G. Studies and Research in Industrial Chemistry, Kuvempu UniversityDepartment of P.G. Studies and Research in Industrial Chemistry, Kuvempu UniversityNational Assessment and Accreditation Council (NAAC)Jain UniversityAbstract In this proposed work, direct green 6 (DG6) decorated carbon paste electrode (CPE) was fabricated for the efficient simultaneous and individual sensing of catechol (CA) and hydroquinone (HY). Electrochemical deeds of the CA and HY were carried out by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) at poly-DG6-modfied carbon paste electrode (Po-DG6-MCPE). Using scanning electron microscopy (SEM) studied the surface property of unmodified CPE (UCPE) and Po-DG6-MCPE. The decorated sensor displayed admirable electrocatalytic performance with fine stability, reproducibility, selectivity, low limit of detection (LLOD) for HY (0.11 μM) and CC (0.09 μM) and sensor process was originated to be adsorption-controlled phenomena. The Po-DG6-MCPE sensor exhibits well separated two peaks for HY and CA in CV and DPV analysis with potential difference of 0.098 V. Subsequently, the sensor was practically applied for the analysis in tap water and it consistent in-between for CA 93.25–100.16% and for HY 97.25–99.87% respectively.https://doi.org/10.1038/s41598-021-93749-w |
| spellingShingle | K. Chetankumar B. E. Kumara Swamy S. C. Sharma S. A. Hariprasad An efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode Scientific Reports |
| title | An efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode |
| title_full | An efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode |
| title_fullStr | An efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode |
| title_full_unstemmed | An efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode |
| title_short | An efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode |
| title_sort | efficient electrochemical sensing of hazardous catechol and hydroquinone at direct green 6 decorated carbon paste electrode |
| url | https://doi.org/10.1038/s41598-021-93749-w |
| work_keys_str_mv | AT kchetankumar anefficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode AT bekumaraswamy anefficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode AT scsharma anefficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode AT sahariprasad anefficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode AT kchetankumar efficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode AT bekumaraswamy efficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode AT scsharma efficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode AT sahariprasad efficientelectrochemicalsensingofhazardouscatecholandhydroquinoneatdirectgreen6decoratedcarbonpasteelectrode |