Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheres

Thinness, lightness, width, strength are people's pursuit of efficient electromagnetic wave (EMW) absorption materials. Fe/Fe3C/Fe3O4@C magnetic microspheres were prepared by high temperature calcination of food-grade ferric citrate and source through hydrothermal reaction. By changing the mola...

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Main Authors: JIANG Weiting, LI Cuiping, JIANG Xiaohui, YU Liangmin
Format: Article
Language:zho
Published: Journal of Materials Engineering 2022-11-01
Series:Cailiao gongcheng
Subjects:
Online Access:http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2021.001144
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author JIANG Weiting
LI Cuiping
JIANG Xiaohui
YU Liangmin
author_facet JIANG Weiting
LI Cuiping
JIANG Xiaohui
YU Liangmin
author_sort JIANG Weiting
collection DOAJ
description Thinness, lightness, width, strength are people's pursuit of efficient electromagnetic wave (EMW) absorption materials. Fe/Fe3C/Fe3O4@C magnetic microspheres were prepared by high temperature calcination of food-grade ferric citrate and source through hydrothermal reaction. By changing the molar ratio of ferric citrate and sucrose, the influence of the content of ferric citrate on the EMW absorption performance of the composite was investigated, and the electromagnetic parameters were effectively controlled to optimize impedance matching. The experimental results show that when the molar ratio of iron citrate and sucrose is 5:3, it has better EMW absorption performance: when the thickness is 2.5 mm, the minimum reflection loss (RL) is -50.17 dB, and the effective absorption band width less than -10 dB is 3.52 GHz. The excellent EMW performance is mainly due to the synergistic effect of the rich interface, porous structure and magnetic properties of Fe/Fe3C/Fe3O4.
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spelling doaj.art-d3544faea55f4e56bcc87a2edc6b6d162023-01-03T11:18:59ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43812022-11-015011819110.11868/j.issn.1001-4381.2021.00114420221108Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheresJIANG Weiting0LI Cuiping1JIANG Xiaohui2YU Liangmin3Key Laboratory of Marine Chemistry Theory and Technology(Ministry of Education), Ocean University of China, Qingdao 266100, Shandong, ChinaNanomaterials Engineering Research Center, Henan University, Kaifeng 475004, Henan, ChinaKey Laboratory of Marine Chemistry Theory and Technology(Ministry of Education), Ocean University of China, Qingdao 266100, Shandong, ChinaKey Laboratory of Marine Chemistry Theory and Technology(Ministry of Education), Ocean University of China, Qingdao 266100, Shandong, ChinaThinness, lightness, width, strength are people's pursuit of efficient electromagnetic wave (EMW) absorption materials. Fe/Fe3C/Fe3O4@C magnetic microspheres were prepared by high temperature calcination of food-grade ferric citrate and source through hydrothermal reaction. By changing the molar ratio of ferric citrate and sucrose, the influence of the content of ferric citrate on the EMW absorption performance of the composite was investigated, and the electromagnetic parameters were effectively controlled to optimize impedance matching. The experimental results show that when the molar ratio of iron citrate and sucrose is 5:3, it has better EMW absorption performance: when the thickness is 2.5 mm, the minimum reflection loss (RL) is -50.17 dB, and the effective absorption band width less than -10 dB is 3.52 GHz. The excellent EMW performance is mainly due to the synergistic effect of the rich interface, porous structure and magnetic properties of Fe/Fe3C/Fe3O4.http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2021.001144sucrosefe/fe3c/fe3o4@c magnetic microsphereelectromagnetic absorbing materialsynergistic reaction
spellingShingle JIANG Weiting
LI Cuiping
JIANG Xiaohui
YU Liangmin
Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheres
Cailiao gongcheng
sucrose
fe/fe3c/fe3o4@c magnetic microsphere
electromagnetic absorbing material
synergistic reaction
title Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheres
title_full Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheres
title_fullStr Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheres
title_full_unstemmed Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheres
title_short Preparation and absorbing properties of Fe/Fe3C/Fe3O4@C magnetic microspheres
title_sort preparation and absorbing properties of fe fe3c fe3o4 c magnetic microspheres
topic sucrose
fe/fe3c/fe3o4@c magnetic microsphere
electromagnetic absorbing material
synergistic reaction
url http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2021.001144
work_keys_str_mv AT jiangweiting preparationandabsorbingpropertiesoffefe3cfe3o4cmagneticmicrospheres
AT licuiping preparationandabsorbingpropertiesoffefe3cfe3o4cmagneticmicrospheres
AT jiangxiaohui preparationandabsorbingpropertiesoffefe3cfe3o4cmagneticmicrospheres
AT yuliangmin preparationandabsorbingpropertiesoffefe3cfe3o4cmagneticmicrospheres