catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]]
The title compound, {(C13H22N4)[Ag2I4]}n, was prepared by reaction of 1,3-bis(N-ethylimidazolium-1-yl)propane iodide with silver (I) oxide. In the 3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) cation, the dihedral angle between the imidazole rings is 49.3&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812020715 |
| _version_ | 1818500188427255808 |
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| author | Jian-Zhong Huo Zhi-Xiang Zhao Men-Chao Shi Hui-Long Li Qing-Xiang Liu |
| author_facet | Jian-Zhong Huo Zhi-Xiang Zhao Men-Chao Shi Hui-Long Li Qing-Xiang Liu |
| author_sort | Jian-Zhong Huo |
| collection | DOAJ |
| description | The title compound, {(C13H22N4)[Ag2I4]}n, was prepared by reaction of 1,3-bis(N-ethylimidazolium-1-yl)propane iodide with silver (I) oxide. In the 3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) cation, the dihedral angle between the imidazole rings is 49.3 (1)°. In the [Ag2I4]2− anion, each AgI atom is bonded to three iodide anions, the two AgI atoms and two of the iodides forming Ag2I2 square-planar (r.m.s. deviation = 0.01 Å) units·The remaining two iodides, which are placed on opposite sides of the square, together with their centrosymmetric counterparts, link the square-planar Ag2I2 units into {[Ag2I4]2−}n polymeric chains via Ag—I bonds. |
| first_indexed | 2024-12-10T20:39:27Z |
| format | Article |
| id | doaj.art-d3569d91c26b4d3ea5bdf703cb761288 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:39:27Z |
| publishDate | 2012-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d3569d91c26b4d3ea5bdf703cb7612882022-12-22T01:34:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m787m78710.1107/S1600536812020715catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]]Jian-Zhong HuoZhi-Xiang ZhaoMen-Chao ShiHui-Long LiQing-Xiang LiuThe title compound, {(C13H22N4)[Ag2I4]}n, was prepared by reaction of 1,3-bis(N-ethylimidazolium-1-yl)propane iodide with silver (I) oxide. In the 3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) cation, the dihedral angle between the imidazole rings is 49.3 (1)°. In the [Ag2I4]2− anion, each AgI atom is bonded to three iodide anions, the two AgI atoms and two of the iodides forming Ag2I2 square-planar (r.m.s. deviation = 0.01 Å) units·The remaining two iodides, which are placed on opposite sides of the square, together with their centrosymmetric counterparts, link the square-planar Ag2I2 units into {[Ag2I4]2−}n polymeric chains via Ag—I bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812020715 |
| spellingShingle | Jian-Zhong Huo Zhi-Xiang Zhao Men-Chao Shi Hui-Long Li Qing-Xiang Liu catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]] Acta Crystallographica Section E |
| title | catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]] |
| title_full | catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]] |
| title_fullStr | catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]] |
| title_full_unstemmed | catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]] |
| title_short | catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-diyl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]] |
| title_sort | catena poly 3 3 amp 8242 diethyl 1 1 amp 8242 propane 1 3 diyl di 1h imidazol 3 ium silver i di amp 956 iodido silver i di amp 956 iodido |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812020715 |
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