Graphite electrode modified with Indigo Carmine for Cu(II) ions detection

An electrochemical method for Cu(II) determination, based on its reaction with indigo carmine (IC) in alkaline medium and differential pulse voltammetry performed at graphite electrode, was elaborated. The experimental parameters affecting the Cu(II) - IC complex formation (reaction time and pH) wer...

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Bibliographic Details
Main Authors: Coulibaly Mariame, Mureşan Liana Maria, Popescu Ionel Cătălin
Format: Article
Language:English
Published: EDP Sciences 2014-07-01
Series:E3S Web of Conferences
Subjects:
Online Access:http://dx.doi.org/10.1051/e3sconf/20130141035
Description
Summary:An electrochemical method for Cu(II) determination, based on its reaction with indigo carmine (IC) in alkaline medium and differential pulse voltammetry performed at graphite electrode, was elaborated. The experimental parameters affecting the Cu(II) - IC complex formation (reaction time and pH) were optimized. The linear range of the calibration curve, obtaining by representing the IC oxidation current (Eappl = 0.175 V vs. Ag/AgCl,KClsat) versus the Cu(II) concentration (pH 10), was from 10 μM up to 70 μM Cu (II) and the detection limit was 4.74 μM.
ISSN:2267-1242