A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application
Submicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coeffic...
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Format: | Article |
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MDPI AG
2023-04-01
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Series: | Energies |
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Online Access: | https://www.mdpi.com/1996-1073/16/9/3774 |
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author | Zinovi Dashevsky Sergii Mamykin Bohdan Dzundza Mark Auslender Roni Z. Shneck |
author_facet | Zinovi Dashevsky Sergii Mamykin Bohdan Dzundza Mark Auslender Roni Z. Shneck |
author_sort | Zinovi Dashevsky |
collection | DOAJ |
description | Submicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coefficient of lead chalcogenide films is attributed to a potential relief that is built along the grain boundaries. It scatters charge carriers with low energy and does not affect carriers with higher energy. The model that accounts for the thermoelectric properties of the films is described and assessed experimentally. The application of a flexible thermoelectric device (module) based on the nanocrystalline film thermoelectric semiconductors as high sensitivity radiation detectors is suggested. |
first_indexed | 2024-03-11T04:20:35Z |
format | Article |
id | doaj.art-d38a7d3a519a486ca43246a86221790f |
institution | Directory Open Access Journal |
issn | 1996-1073 |
language | English |
last_indexed | 2024-03-11T04:20:35Z |
publishDate | 2023-04-01 |
publisher | MDPI AG |
record_format | Article |
series | Energies |
spelling | doaj.art-d38a7d3a519a486ca43246a86221790f2023-11-17T22:51:34ZengMDPI AGEnergies1996-10732023-04-01169377410.3390/en16093774A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and ApplicationZinovi Dashevsky0Sergii Mamykin1Bohdan Dzundza2Mark Auslender3Roni Z. Shneck4Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, IsraelV.E. Lashkaryov Institute of Semiconductor Physics, National Academy of Sciences of Ukraine, 03028 Kyiv, UkraineDepartment of Computer Engineering and Electronics, Vasyl Stefanyk Precarpathian National University, 76018 Ivano-Frankivsk, UkraineSchool of Electrical and Computer Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, IsraelDepartment of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, IsraelSubmicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coefficient of lead chalcogenide films is attributed to a potential relief that is built along the grain boundaries. It scatters charge carriers with low energy and does not affect carriers with higher energy. The model that accounts for the thermoelectric properties of the films is described and assessed experimentally. The application of a flexible thermoelectric device (module) based on the nanocrystalline film thermoelectric semiconductors as high sensitivity radiation detectors is suggested.https://www.mdpi.com/1996-1073/16/9/3774thermoelectric materialsnanostructuringfigure of meritfilm thermoelectric module |
spellingShingle | Zinovi Dashevsky Sergii Mamykin Bohdan Dzundza Mark Auslender Roni Z. Shneck A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application Energies thermoelectric materials nanostructuring figure of merit film thermoelectric module |
title | A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application |
title_full | A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application |
title_fullStr | A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application |
title_full_unstemmed | A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application |
title_short | A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application |
title_sort | review of nanocrystalline film thermoelectrics on lead chalcogenide semiconductors progress and application |
topic | thermoelectric materials nanostructuring figure of merit film thermoelectric module |
url | https://www.mdpi.com/1996-1073/16/9/3774 |
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