A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application

Submicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coeffic...

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Main Authors: Zinovi Dashevsky, Sergii Mamykin, Bohdan Dzundza, Mark Auslender, Roni Z. Shneck
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/9/3774
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author Zinovi Dashevsky
Sergii Mamykin
Bohdan Dzundza
Mark Auslender
Roni Z. Shneck
author_facet Zinovi Dashevsky
Sergii Mamykin
Bohdan Dzundza
Mark Auslender
Roni Z. Shneck
author_sort Zinovi Dashevsky
collection DOAJ
description Submicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coefficient of lead chalcogenide films is attributed to a potential relief that is built along the grain boundaries. It scatters charge carriers with low energy and does not affect carriers with higher energy. The model that accounts for the thermoelectric properties of the films is described and assessed experimentally. The application of a flexible thermoelectric device (module) based on the nanocrystalline film thermoelectric semiconductors as high sensitivity radiation detectors is suggested.
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spelling doaj.art-d38a7d3a519a486ca43246a86221790f2023-11-17T22:51:34ZengMDPI AGEnergies1996-10732023-04-01169377410.3390/en16093774A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and ApplicationZinovi Dashevsky0Sergii Mamykin1Bohdan Dzundza2Mark Auslender3Roni Z. Shneck4Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, IsraelV.E. Lashkaryov Institute of Semiconductor Physics, National Academy of Sciences of Ukraine, 03028 Kyiv, UkraineDepartment of Computer Engineering and Electronics, Vasyl Stefanyk Precarpathian National University, 76018 Ivano-Frankivsk, UkraineSchool of Electrical and Computer Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, IsraelDepartment of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105, IsraelSubmicron-structured films of thermoelectric materials, exhibiting an improved thermoelectric figure of merit, are reviewed, including methods of fabrication and characterization. The review emphasizes the beneficial role of the grain boundaries in polycrystalline films. The enhanced Seebeck coefficient of lead chalcogenide films is attributed to a potential relief that is built along the grain boundaries. It scatters charge carriers with low energy and does not affect carriers with higher energy. The model that accounts for the thermoelectric properties of the films is described and assessed experimentally. The application of a flexible thermoelectric device (module) based on the nanocrystalline film thermoelectric semiconductors as high sensitivity radiation detectors is suggested.https://www.mdpi.com/1996-1073/16/9/3774thermoelectric materialsnanostructuringfigure of meritfilm thermoelectric module
spellingShingle Zinovi Dashevsky
Sergii Mamykin
Bohdan Dzundza
Mark Auslender
Roni Z. Shneck
A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application
Energies
thermoelectric materials
nanostructuring
figure of merit
film thermoelectric module
title A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application
title_full A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application
title_fullStr A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application
title_full_unstemmed A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application
title_short A Review of Nanocrystalline Film Thermoelectrics on Lead Chalcogenide Semiconductors: Progress and Application
title_sort review of nanocrystalline film thermoelectrics on lead chalcogenide semiconductors progress and application
topic thermoelectric materials
nanostructuring
figure of merit
film thermoelectric module
url https://www.mdpi.com/1996-1073/16/9/3774
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