| Summary: | High temperature is required in carbon fiber synthesis in the carbonization step. However, direct high-temperature heating without the presence of additive materials would affect the yield and structure of carbon fibers produced. Thus, this study aims to synthesize carbon fibers from poly-vinyl alcohol (PVA), as the precursor and reducing agent, using silver nanoparticles (SNP) from silver nitrate (AgNO<sub>3</sub>) as additives. The pre-treatment of PVA was performed in three steps, i.e., mixing PVA/AgNO<sub>3</sub>, electrospinning, and iodination. The interaction of PVA and AgNO<sub>3</sub> was assessed by FTIR, and SEM was used to characterize the electro-spun fibers prior and after iodination; Raman spectrophotometer was carried out to confirm the yield of carbon fibers. There was reduction in oxygen groups (3000–3800 cm<sup>−1</sup>) and emergence of –C=O (1100 cm<sup>−1</sup>) and –C=C– (1627 cm<sup>−1</sup>) functional groups, indicating formation of carbon layers. Based on the DT/GA results, the silver nanoparticles reduce the need of high temperature with optimum carbonization at 350 °C and lead to the formation of more regular graphene layers. Graphene layers with a size distribution of 0.438 nm and well-organized structures were successfully formed, and the Raman shifting showed higher intensities of G and G’ bands in the presence of Ag. Based on DT/GA results, the yield of carbon fibers with iodinated PVA fibers and SNP as additive had higher rates around 800 µg/min, reaching 33% at 500 °C. Thus, it is demonstrated that iodinated PVA/AgNO<sub>3</sub> samples can significantly improve carbon fiber yield at low temperatures.
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