Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts
Cationic polymerization of β-pinene, a naturally occurring monomer, was studied in the presence of different alkylaluminum chlorides ((iBu)3Al2Cl3, Et3Al2Cl3 и Мe2AlCl) in the solvent mixture dichloromethane/methylcyclohexane (DCM/MCH) at –78 °C. The effect of catalyst concentration [(iBu)3Al2Cl3] a...
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| Format: | Article |
| Language: | Belarusian |
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Belarusian State University
2020-08-01
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| Series: | Журнал Белорусского государственного университета: Химия |
| Subjects: | |
| Online Access: | https://journals.bsu.by/index.php/chemistry/article/view/3269 |
| _version_ | 1818873777980702720 |
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| author | Maksim I. Hulnik Olga V. Kuharenko Sergei V. Kostjuk |
| author_facet | Maksim I. Hulnik Olga V. Kuharenko Sergei V. Kostjuk |
| author_sort | Maksim I. Hulnik |
| collection | DOAJ |
| description | Cationic polymerization of β-pinene, a naturally occurring monomer, was studied in the presence of different alkylaluminum chlorides ((iBu)3Al2Cl3, Et3Al2Cl3 и Мe2AlCl) in the solvent mixture dichloromethane/methylcyclohexane (DCM/MCH) at –78 °C. The effect of catalyst concentration [(iBu)3Al2Cl3] and various electron donors on the polymerization rat and molecular-weight characteristics of synthesized poly(β-pinenes) was investigated. Controlled cationic polymerization of β-pinene was carried out in the presence СumCl/Мe2AlCl initiating system. The polymers with controlled molecular weight up to 6400 g/mol and relatively low polydispersity (Mw/Mn < 1.42) were synthesized. Microstructure of synthesized poly(β-pinene) was investigated by 1H NMR spectroscopy. |
| first_indexed | 2024-12-19T13:00:06Z |
| format | Article |
| id | doaj.art-d3b3a18d480f49b69502286d3504570d |
| institution | Directory Open Access Journal |
| issn | 2520-257X 2617-3980 |
| language | Belarusian |
| last_indexed | 2024-12-19T13:00:06Z |
| publishDate | 2020-08-01 |
| publisher | Belarusian State University |
| record_format | Article |
| series | Журнал Белорусского государственного университета: Химия |
| spelling | doaj.art-d3b3a18d480f49b69502286d3504570d2022-12-21T20:20:16ZbelBelarusian State UniversityЖурнал Белорусского государственного университета: Химия2520-257X2617-39802020-08-0129810710.33581/2520-257X-2020-2-98-1073269Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalystsMaksim I. Hulnik0Olga V. Kuharenko1Sergei V. Kostjuk2https://orcid.org/0000-0002-7466-3662Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus; Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, BelarusBelarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus; Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, BelarusResearch Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, BelarusCationic polymerization of β-pinene, a naturally occurring monomer, was studied in the presence of different alkylaluminum chlorides ((iBu)3Al2Cl3, Et3Al2Cl3 и Мe2AlCl) in the solvent mixture dichloromethane/methylcyclohexane (DCM/MCH) at –78 °C. The effect of catalyst concentration [(iBu)3Al2Cl3] and various electron donors on the polymerization rat and molecular-weight characteristics of synthesized poly(β-pinenes) was investigated. Controlled cationic polymerization of β-pinene was carried out in the presence СumCl/Мe2AlCl initiating system. The polymers with controlled molecular weight up to 6400 g/mol and relatively low polydispersity (Mw/Mn < 1.42) were synthesized. Microstructure of synthesized poly(β-pinene) was investigated by 1H NMR spectroscopy.https://journals.bsu.by/index.php/chemistry/article/view/3269β-pinenecationic polymerizationalkylaluminum chloridescontrolled cationic polymerizationelectron donorproton trap |
| spellingShingle | Maksim I. Hulnik Olga V. Kuharenko Sergei V. Kostjuk Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts Журнал Белорусского государственного университета: Химия β-pinene cationic polymerization alkylaluminum chlorides controlled cationic polymerization electron donor proton trap |
| title | Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts |
| title_full | Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts |
| title_fullStr | Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts |
| title_full_unstemmed | Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts |
| title_short | Cationic polymerization of β-pinene in the presence of alkylaluminum chlorides as catalysts |
| title_sort | cationic polymerization of β pinene in the presence of alkylaluminum chlorides as catalysts |
| topic | β-pinene cationic polymerization alkylaluminum chlorides controlled cationic polymerization electron donor proton trap |
| url | https://journals.bsu.by/index.php/chemistry/article/view/3269 |
| work_keys_str_mv | AT maksimihulnik cationicpolymerizationofbpineneinthepresenceofalkylaluminumchloridesascatalysts AT olgavkuharenko cationicpolymerizationofbpineneinthepresenceofalkylaluminumchloridesascatalysts AT sergeivkostjuk cationicpolymerizationofbpineneinthepresenceofalkylaluminumchloridesascatalysts |