Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane
The development of highly active and stable catalysts is desirable for hydrogen generation from ammonia borane (AB). In this study, Ni0.25Co0.75O nanowire array supported on Cu@CuO foam (Ni0.25Co0.75O/Cu@CuO) has been successfully fabricated. The Ni0.25Co0.75O/Cu@CuO catalyst exhibited high performa...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2021-11-01
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| Series: | Catalysis Communications |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736721000662 |
| _version_ | 1818722372973232128 |
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| author | Yufa Feng Fei Lv Huize Wang Xiaodong Chen Hang Li Zhiyu Chen Guangyu Lin Jinyun Liao Mingyang He Quanbing Liu |
| author_facet | Yufa Feng Fei Lv Huize Wang Xiaodong Chen Hang Li Zhiyu Chen Guangyu Lin Jinyun Liao Mingyang He Quanbing Liu |
| author_sort | Yufa Feng |
| collection | DOAJ |
| description | The development of highly active and stable catalysts is desirable for hydrogen generation from ammonia borane (AB). In this study, Ni0.25Co0.75O nanowire array supported on Cu@CuO foam (Ni0.25Co0.75O/Cu@CuO) has been successfully fabricated. The Ni0.25Co0.75O/Cu@CuO catalyst exhibited high performance towards AB hydrolysis with a high hydrogen generation rate (HGR) of 4.348 Lhydrogen min−1 gcat.−1. More importantly, the activity of Ni0.25Co0.75O/Cu@CuO has only decreased slightly after twelve cycles. This work provides a simple method to fabricate an inexpensive film catalyst with high activity and good stability for ammonia borane hydrolysis. |
| first_indexed | 2024-12-17T20:53:35Z |
| format | Article |
| id | doaj.art-d3e4de6b62ba4370aafe692b4462b21c |
| institution | Directory Open Access Journal |
| issn | 1873-3905 |
| language | English |
| last_indexed | 2024-12-17T20:53:35Z |
| publishDate | 2021-11-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Catalysis Communications |
| spelling | doaj.art-d3e4de6b62ba4370aafe692b4462b21c2022-12-21T21:32:57ZengElsevierCatalysis Communications1873-39052021-11-01159106343Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia boraneYufa Feng0Fei Lv1Huize Wang2Xiaodong Chen3Hang Li4Zhiyu Chen5Guangyu Lin6Jinyun Liao7Mingyang He8Quanbing Liu9Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, China; School of chemistry and Materials Engineering, Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, ChinaCenter of Comprehensive Technology, Huizhou Customs, Huizhou 516006, ChinaSchool of chemistry and Materials Engineering, Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, China; Corresponding authors.School of chemistry and Materials Engineering, Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, ChinaSchool of chemistry and Materials Engineering, Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, ChinaSchool of chemistry and Materials Engineering, Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, ChinaSchool of chemistry and Materials Engineering, Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, ChinaSchool of chemistry and Materials Engineering, Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, China; Corresponding authors.Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, China; Corresponding authors.Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, ChinaThe development of highly active and stable catalysts is desirable for hydrogen generation from ammonia borane (AB). In this study, Ni0.25Co0.75O nanowire array supported on Cu@CuO foam (Ni0.25Co0.75O/Cu@CuO) has been successfully fabricated. The Ni0.25Co0.75O/Cu@CuO catalyst exhibited high performance towards AB hydrolysis with a high hydrogen generation rate (HGR) of 4.348 Lhydrogen min−1 gcat.−1. More importantly, the activity of Ni0.25Co0.75O/Cu@CuO has only decreased slightly after twelve cycles. This work provides a simple method to fabricate an inexpensive film catalyst with high activity and good stability for ammonia borane hydrolysis.http://www.sciencedirect.com/science/article/pii/S1566736721000662Heterogeneous catalysisNanowire arrayHydrogen generationAmmonia borane hydrolysis |
| spellingShingle | Yufa Feng Fei Lv Huize Wang Xiaodong Chen Hang Li Zhiyu Chen Guangyu Lin Jinyun Liao Mingyang He Quanbing Liu Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane Catalysis Communications Heterogeneous catalysis Nanowire array Hydrogen generation Ammonia borane hydrolysis |
| title | Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane |
| title_full | Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane |
| title_fullStr | Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane |
| title_full_unstemmed | Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane |
| title_short | Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane |
| title_sort | ni0 25co0 75o nanowire array supported on cu cuo foam an inexpensive and durable catalyst for hydrogen generation from ammonia borane |
| topic | Heterogeneous catalysis Nanowire array Hydrogen generation Ammonia borane hydrolysis |
| url | http://www.sciencedirect.com/science/article/pii/S1566736721000662 |
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