Hydroxyl-Decorated Diiron Complex as a [FeFe]-Hydrogenase Active Site Model Complex: Light-Driven Photocatalytic Activity and Heterogenization on Ethylene-Bridged Periodic Mesoporous Organosilica

Hydroxyl-Decorated Diiron Complex as a [FeFe]-Hydrogenase Active Site Model Complex: Light-Driven Photocatalytic Activity and Heterogenization on Ethylene-Bridged Periodic Mesoporous Organosilica

A biomimetic model complex of the [FeFe]-hydrogenase active site (FeFeOH) with an ethylene bridge and a pendant hydroxyl group has been synthesized, characterized and evaluated as catalyst for the light-driven hydrogen production. The interaction of the hydroxyl group present in the complex with 3-i...

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Bibliographic Details
Main Authors: Juan Amaro-Gahete, Dolores Esquivel, Mariia V. Pavliuk, César Jiménez-Sanchidrián, Haining Tian, Sascha Ott, Francisco J. Romero-Salguero
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Catalysts
Subjects:
[FeFe]-hydrogenase
periodic mesoporous organosilica
biomimetic chemistry
artificial photosynthesis
light-driven hydrogen evolution
Online Access:https://www.mdpi.com/2073-4344/12/3/254

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