Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products

Organosolv lignin is an emerging bio-additive for creating functional properties in various products with its advantages in high-purity, sulfur-free, biocompatibility, and solubility in green solvents. In this study, effects of thermal and physical modification on alterations of functional propertie...

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Main Authors: Chayanon Chotirotsukon, Kunlanis Jirachavala, Marisa Raita, Suchat Pongchaiphol, Bongkot Hararak, Navadol Laosiripojana, Verawat Champreda
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-02-01
Series:Frontiers in Chemical Engineering
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fceng.2023.1099010/full
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author Chayanon Chotirotsukon
Chayanon Chotirotsukon
Kunlanis Jirachavala
Kunlanis Jirachavala
Marisa Raita
Marisa Raita
Suchat Pongchaiphol
Suchat Pongchaiphol
Bongkot Hararak
Navadol Laosiripojana
Navadol Laosiripojana
Verawat Champreda
Verawat Champreda
author_facet Chayanon Chotirotsukon
Chayanon Chotirotsukon
Kunlanis Jirachavala
Kunlanis Jirachavala
Marisa Raita
Marisa Raita
Suchat Pongchaiphol
Suchat Pongchaiphol
Bongkot Hararak
Navadol Laosiripojana
Navadol Laosiripojana
Verawat Champreda
Verawat Champreda
author_sort Chayanon Chotirotsukon
collection DOAJ
description Organosolv lignin is an emerging bio-additive for creating functional properties in various products with its advantages in high-purity, sulfur-free, biocompatibility, and solubility in green solvents. In this study, effects of thermal and physical modification on alterations of functional properties and particle size distribution of isolated organosolv lignin from sugarcane bagasse (OLB) were studied. Thermal treatment of OLB at increasing temperatures from 170 to 230°C in 70%w/w aqueous ethanol led to alteration of phenolic hydroxyl content, while ultrasonication resulted in homogeneous size distribution of the modified OLB according to laser diffraction and scanning electron micrograph. The highest ultraviolet light absorbance and antioxidant activities were obtained at 190°C treatment which were correlated to the highest phenolic group content. Application of the modified OLB at 3% w/w in a base cream formulation resulted in enhancement of the anti-UV activity to exceed SPF 50 with increasing antioxidant activity in the product. The work provides basis on modification of organosolv lignin for application as a potent functional additive in cosmeceutical products.
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spelling doaj.art-d428ada904794666b073234e94d6b79b2023-02-22T14:30:26ZengFrontiers Media S.A.Frontiers in Chemical Engineering2673-27182023-02-01510.3389/fceng.2023.10990101099010Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical productsChayanon Chotirotsukon0Chayanon Chotirotsukon1Kunlanis Jirachavala2Kunlanis Jirachavala3Marisa Raita4Marisa Raita5Suchat Pongchaiphol6Suchat Pongchaiphol7Bongkot Hararak8Navadol Laosiripojana9Navadol Laosiripojana10Verawat Champreda11Verawat Champreda12BIOTEC-JGSEE Integrated Biorefinery Laboratory, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandBiorefinery and Bioproduct Technology Research Group, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandBIOTEC-JGSEE Integrated Biorefinery Laboratory, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandBiorefinery and Bioproduct Technology Research Group, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandBIOTEC-JGSEE Integrated Biorefinery Laboratory, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandBiorefinery and Bioproduct Technology Research Group, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandBIOTEC-JGSEE Integrated Biorefinery Laboratory, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandThe Joint Graduate School of Energy and Environment, King Mongkut’s University of Technology Thonburi, Bangkok, ThailandNational Metal and Materials Technology Center (MTEC), National Science and Technology Development Agency, Khlong-Nueng, ThailandBIOTEC-JGSEE Integrated Biorefinery Laboratory, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandThe Joint Graduate School of Energy and Environment, King Mongkut’s University of Technology Thonburi, Bangkok, ThailandBIOTEC-JGSEE Integrated Biorefinery Laboratory, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandBiorefinery and Bioproduct Technology Research Group, National Center for Genetic Engineering and Biotechnology, Khlong Luang, ThailandOrganosolv lignin is an emerging bio-additive for creating functional properties in various products with its advantages in high-purity, sulfur-free, biocompatibility, and solubility in green solvents. In this study, effects of thermal and physical modification on alterations of functional properties and particle size distribution of isolated organosolv lignin from sugarcane bagasse (OLB) were studied. Thermal treatment of OLB at increasing temperatures from 170 to 230°C in 70%w/w aqueous ethanol led to alteration of phenolic hydroxyl content, while ultrasonication resulted in homogeneous size distribution of the modified OLB according to laser diffraction and scanning electron micrograph. The highest ultraviolet light absorbance and antioxidant activities were obtained at 190°C treatment which were correlated to the highest phenolic group content. Application of the modified OLB at 3% w/w in a base cream formulation resulted in enhancement of the anti-UV activity to exceed SPF 50 with increasing antioxidant activity in the product. The work provides basis on modification of organosolv lignin for application as a potent functional additive in cosmeceutical products.https://www.frontiersin.org/articles/10.3389/fceng.2023.1099010/fullorganosol ligninanti UVAntio×idantthermal modifcationfunctional additive
spellingShingle Chayanon Chotirotsukon
Chayanon Chotirotsukon
Kunlanis Jirachavala
Kunlanis Jirachavala
Marisa Raita
Marisa Raita
Suchat Pongchaiphol
Suchat Pongchaiphol
Bongkot Hararak
Navadol Laosiripojana
Navadol Laosiripojana
Verawat Champreda
Verawat Champreda
Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products
Frontiers in Chemical Engineering
organosol lignin
anti UV
Antio×idant
thermal modifcation
functional additive
title Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products
title_full Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products
title_fullStr Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products
title_full_unstemmed Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products
title_short Effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products
title_sort effects of thermal and physical modification on functional properties of organosolv lignin from sugarcane bagasse and its application in cosmeceutical products
topic organosol lignin
anti UV
Antio×idant
thermal modifcation
functional additive
url https://www.frontiersin.org/articles/10.3389/fceng.2023.1099010/full
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