Scanning Tunneling Microscopy and Spectroscopy of Supported Nanostructures

Recent advances in low-temperature scanning tunneling microscopy (STM) and spectroscopy (STS) have provided new opportunities for the investigation of the local geometric, electronic, magnetic, and optical properties of nanostructures. This review focuses on the presentation and discussion...

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Main Author: Wolf-Dieter Schneider
Format: Article
Language:deu
Published: Swiss Chemical Society 2012-02-01
Series:CHIMIA
Subjects:
Online Access:https://www.chimia.ch/chimia/article/view/5153
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author Wolf-Dieter Schneider
author_facet Wolf-Dieter Schneider
author_sort Wolf-Dieter Schneider
collection DOAJ
description Recent advances in low-temperature scanning tunneling microscopy (STM) and spectroscopy (STS) have provided new opportunities for the investigation of the local geometric, electronic, magnetic, and optical properties of nanostructures. This review focuses on the presentation and discussion of single molecules, supramolecular assemblies, and other nanostructures; all research results obtained in our laboratory. The emphasis is directed to the observation of new effects, where the properties of matter at the nanoscale differ from those at the mesoscopic or macroscopic scale: small is different. This fact is illustrated for the conservation of chirality in a hierarchical supramolecular assembly of organic molecules and for local light emission from supported molecules. The latter indicates a possible route towards an optical spectroscopic analysis on the scale of single molecules.
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spelling doaj.art-d437d8060f9e4e458919a80ecdf35b662022-12-22T00:01:07ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242012-02-01661-210.2533/chimia.2012.16Scanning Tunneling Microscopy and Spectroscopy of Supported NanostructuresWolf-Dieter Schneider0Ecole Polytechnique Fédérale de Lausanne (EPFL) Institut de Physique de la Matière Condensée CH-1015 Lausanne, Switzerland. wolf-dieter.schneider@epfl.ch Recent advances in low-temperature scanning tunneling microscopy (STM) and spectroscopy (STS) have provided new opportunities for the investigation of the local geometric, electronic, magnetic, and optical properties of nanostructures. This review focuses on the presentation and discussion of single molecules, supramolecular assemblies, and other nanostructures; all research results obtained in our laboratory. The emphasis is directed to the observation of new effects, where the properties of matter at the nanoscale differ from those at the mesoscopic or macroscopic scale: small is different. This fact is illustrated for the conservation of chirality in a hierarchical supramolecular assembly of organic molecules and for local light emission from supported molecules. The latter indicates a possible route towards an optical spectroscopic analysis on the scale of single molecules. https://www.chimia.ch/chimia/article/view/5153Scanning tunneling microscopySingle molecule luminescenceSupramolecular self-assemblySurface chirality
spellingShingle Wolf-Dieter Schneider
Scanning Tunneling Microscopy and Spectroscopy of Supported Nanostructures
CHIMIA
Scanning tunneling microscopy
Single molecule luminescence
Supramolecular self-assembly
Surface chirality
title Scanning Tunneling Microscopy and Spectroscopy of Supported Nanostructures
title_full Scanning Tunneling Microscopy and Spectroscopy of Supported Nanostructures
title_fullStr Scanning Tunneling Microscopy and Spectroscopy of Supported Nanostructures
title_full_unstemmed Scanning Tunneling Microscopy and Spectroscopy of Supported Nanostructures
title_short Scanning Tunneling Microscopy and Spectroscopy of Supported Nanostructures
title_sort scanning tunneling microscopy and spectroscopy of supported nanostructures
topic Scanning tunneling microscopy
Single molecule luminescence
Supramolecular self-assembly
Surface chirality
url https://www.chimia.ch/chimia/article/view/5153
work_keys_str_mv AT wolfdieterschneider scanningtunnelingmicroscopyandspectroscopyofsupportednanostructures