{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
In title complex, [Co(C28H22N2O2)(C5H5N)2]ClO4·1.5H2O, the CoIII ion is in a slightly distorted octahedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water mol...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809002293 |
| _version_ | 1818998344164311040 |
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| author | Lian-Wen Zhou |
| author_facet | Lian-Wen Zhou |
| author_sort | Lian-Wen Zhou |
| collection | DOAJ |
| description | In title complex, [Co(C28H22N2O2)(C5H5N)2]ClO4·1.5H2O, the CoIII ion is in a slightly distorted octahedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water molecules and all components are connected via intermolecular O—H...O hydrogen bonds. |
| first_indexed | 2024-12-20T22:00:02Z |
| format | Article |
| id | doaj.art-d452b93786494809aaf6cadefc2dc0e1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:00:02Z |
| publishDate | 2009-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d452b93786494809aaf6cadefc2dc0e12022-12-21T19:25:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m226m22610.1107/S1600536809002293{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrateLian-Wen ZhouIn title complex, [Co(C28H22N2O2)(C5H5N)2]ClO4·1.5H2O, the CoIII ion is in a slightly distorted octahedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water molecules and all components are connected via intermolecular O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809002293 |
| spellingShingle | Lian-Wen Zhou {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate Acta Crystallographica Section E |
| title | {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate |
| title_full | {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate |
| title_fullStr | {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate |
| title_full_unstemmed | {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate |
| title_short | {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate |
| title_sort | 1r 2r 1 2 diphenyl 2 2 8242 ethane 1 2 diylbis nitrilomethylidyne diphenolato dipyridinecobalt iii perchlorate sesquihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809002293 |
| work_keys_str_mv | AT lianwenzhou 1r2r12diphenyl228242ethane12diylbisnitrilomethylidynediphenolatodipyridinecobaltiiiperchloratesesquihydrate |