A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions

Oxidative cleavage of oximes to their parent corresponding carbonyl compounds using potassium dichromate-dimethylformamide system under homogeneous conditions in good yields is described. The main advantage of the present method is no need of preparation of hexavalent chromium-based reagents due to...

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Main Authors: Li-Hong Huang, Ji-Dong Lou, Changhe Zhang, Fang Lin, Xiao-Nan Zou
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/826527
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author Li-Hong Huang
Ji-Dong Lou
Changhe Zhang
Fang Lin
Xiao-Nan Zou
author_facet Li-Hong Huang
Ji-Dong Lou
Changhe Zhang
Fang Lin
Xiao-Nan Zou
author_sort Li-Hong Huang
collection DOAJ
description Oxidative cleavage of oximes to their parent corresponding carbonyl compounds using potassium dichromate-dimethylformamide system under homogeneous conditions in good yields is described. The main advantage of the present method is no need of preparation of hexavalent chromium-based reagents due to using a polar aprotic solvent.
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spelling doaj.art-d464916f6945484b8ce73d73803d325d2022-12-22T03:58:24ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102012-01-01942141214410.1155/2012/826527A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous ConditionsLi-Hong Huang0Ji-Dong Lou1Changhe Zhang2Fang Lin3Xiao-Nan Zou4College of Life Sciences, China Jiliang University, Hangzhou, Zhejiang 310018, ChinaCollege of Life Sciences, China Jiliang University, Hangzhou, Zhejiang 310018, ChinaCentre for the Research and Technology of Agro-environmental and Biological Sciences (CITAB)/Department of Biology and Environment, Universidade de Trás-os-Montes e Alto Douro (UTAD), Apartado 1013, 5001-801 Vila Real, PortugalCollege of Life Sciences, China Jiliang University, Hangzhou, Zhejiang 310018, ChinaCollege of Life Sciences, China Jiliang University, Hangzhou, Zhejiang 310018, ChinaOxidative cleavage of oximes to their parent corresponding carbonyl compounds using potassium dichromate-dimethylformamide system under homogeneous conditions in good yields is described. The main advantage of the present method is no need of preparation of hexavalent chromium-based reagents due to using a polar aprotic solvent.http://dx.doi.org/10.1155/2012/826527
spellingShingle Li-Hong Huang
Ji-Dong Lou
Changhe Zhang
Fang Lin
Xiao-Nan Zou
A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions
E-Journal of Chemistry
title A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions
title_full A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions
title_fullStr A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions
title_full_unstemmed A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions
title_short A Facile Procedure for the Conversion of Oximes to Ketones and Aldehydes with Potassium Dichromate in Dimethylformamide under Homogeneous Conditions
title_sort facile procedure for the conversion of oximes to ketones and aldehydes with potassium dichromate in dimethylformamide under homogeneous conditions
url http://dx.doi.org/10.1155/2012/826527
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