Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV)
The title SnIV complex, [Sn(C6H5)3Cl(C18H15O4P)], is a formal adduct between triphenyl phosphate (PhO)3P=O and the stannane derivative chloridotriphenyltin, SnPh3Cl. The structure refinement reveals that this molecule displays the largest Sn—O bond length for compounds including the X=O→SnPh3Cl frag...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989023000270 |
| _version_ | 1811170153387261952 |
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| author | Serigne Fallou Pouye Sylvain Bernès Lamine Yaffa Waly Diallo Ibrahima Cissé Cheikh Abdoul Khadir Diop Mamadou Sidibé Libasse Diop |
| author_facet | Serigne Fallou Pouye Sylvain Bernès Lamine Yaffa Waly Diallo Ibrahima Cissé Cheikh Abdoul Khadir Diop Mamadou Sidibé Libasse Diop |
| author_sort | Serigne Fallou Pouye |
| collection | DOAJ |
| description | The title SnIV complex, [Sn(C6H5)3Cl(C18H15O4P)], is a formal adduct between triphenyl phosphate (PhO)3P=O and the stannane derivative chloridotriphenyltin, SnPh3Cl. The structure refinement reveals that this molecule displays the largest Sn—O bond length for compounds including the X=O→SnPh3Cl fragment (X = P, S, C, or V), 2.6644 (17) Å. However, an AIM topology analysis based on the wavefunction calculated from the refined X-ray structure shows the presence of a bond critical point (3,−1), lying on the interbasin surface separating the coordinated phosphate O atom and the Sn atom. This study thus shows that an actual polar covalent bond is formed between (PhO)3P=O and SnPh3Cl moieties. |
| first_indexed | 2024-04-10T16:52:28Z |
| format | Article |
| id | doaj.art-d47179005be0474cb1c8e73b7e0385c9 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-10T16:52:28Z |
| publishDate | 2023-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-d47179005be0474cb1c8e73b7e0385c92023-02-07T12:33:19ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-02-017929910210.1107/S2056989023000270zl4052Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV)Serigne Fallou Pouye0Sylvain Bernès1Lamine Yaffa2Waly Diallo3Ibrahima Cissé4Cheikh Abdoul Khadir Diop5Mamadou Sidibé6Libasse Diop7Département de Sciences Appliquées et Technologies Emergentes, Ecole Supérieure des Sciences et Techniques de l'Ingénieur, Université Amadou Mahtar Mbow, BP 45927 Dakar NAFA VDN, Dakar, SenegalInstituto de Física, Benemérita Universidad Autónoma de Puebla, Av. San Claudio y 18 Sur, 72570 Puebla, Pue., MexicoLaboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalDépartement de Sciences Appliquées et Technologies Emergentes, Ecole Supérieure des Sciences et Techniques de l'Ingénieur, Université Amadou Mahtar Mbow, BP 45927 Dakar NAFA VDN, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalThe title SnIV complex, [Sn(C6H5)3Cl(C18H15O4P)], is a formal adduct between triphenyl phosphate (PhO)3P=O and the stannane derivative chloridotriphenyltin, SnPh3Cl. The structure refinement reveals that this molecule displays the largest Sn—O bond length for compounds including the X=O→SnPh3Cl fragment (X = P, S, C, or V), 2.6644 (17) Å. However, an AIM topology analysis based on the wavefunction calculated from the refined X-ray structure shows the presence of a bond critical point (3,−1), lying on the interbasin surface separating the coordinated phosphate O atom and the Sn atom. This study thus shows that an actual polar covalent bond is formed between (PhO)3P=O and SnPh3Cl moieties.http://scripts.iucr.org/cgi-bin/paper?S2056989023000270crystal structurestannanetriphenylphosphateqtaimtopology analysis |
| spellingShingle | Serigne Fallou Pouye Sylvain Bernès Lamine Yaffa Waly Diallo Ibrahima Cissé Cheikh Abdoul Khadir Diop Mamadou Sidibé Libasse Diop Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV) Acta Crystallographica Section E: Crystallographic Communications crystal structure stannane triphenylphosphate qtaim topology analysis |
| title | Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV) |
| title_full | Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV) |
| title_fullStr | Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV) |
| title_full_unstemmed | Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV) |
| title_short | Synthesis and topology analysis of chloridotriphenyl(triphenyl phosphate-κO)tin(IV) |
| title_sort | synthesis and topology analysis of chloridotriphenyl triphenyl phosphate κo tin iv |
| topic | crystal structure stannane triphenylphosphate qtaim topology analysis |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023000270 |
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