Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexico

We analyzed sediments from a core collected on the Pacific coast of Baja California, ~45 km off the city of Tijuana and at 1257 m water depth (32º29.5′N, 117º28.3′W), for trace metal content in two operationally-defined fractions, HCl and pyrite. Our results indicate a transference of Cu > Ni &g...

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Main Authors: C Nava-López, MA Huerta-Díaz
Format: Article
Language:English
Published: Universidad Autónoma de Baja California 2001-03-01
Series:Ciencias Marinas
Subjects:
Online Access:https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/456
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author C Nava-López
MA Huerta-Díaz
author_facet C Nava-López
MA Huerta-Díaz
author_sort C Nava-López
collection DOAJ
description We analyzed sediments from a core collected on the Pacific coast of Baja California, ~45 km off the city of Tijuana and at 1257 m water depth (32º29.5′N, 117º28.3′W), for trace metal content in two operationally-defined fractions, HCl and pyrite. Our results indicate a transference of Cu > Ni > Zn >> Hg and Ag from the HCl to the pyrite fraction. Sediments have degrees of pyritization (DOP) that averaged 7.2 ± 4.9%, with a maximum value of 18.5%. Average degrees of trace metal pyritization (DTMP) ranged from 6.2 ± 2.1% to 83 ± 18% for Mn and Hg, respectively, although maximum values for some metals were close to 100%. This transference is apparently a function of the solubility products of metal sulfides and the relative abundances of metals in the HCl fraction, as suggested by the significant correlation (p < 0.001) observed between these two parameters and the DTMP of a number of trace metals. A similar correlation was obtained from published data of two cores collected in the Gulf of Mexico.
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spelling doaj.art-d482a4d8c788443b83002535d0d4d5e32024-03-03T19:35:50ZengUniversidad Autónoma de Baja CaliforniaCiencias Marinas0185-38802395-90532001-03-0127210.7773/cm.v27i2.456Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexicoC Nava-López0MA Huerta-Díaz1Universidad Autónoma de Baja CaliforniaUniversidad Autónoma de Baja California We analyzed sediments from a core collected on the Pacific coast of Baja California, ~45 km off the city of Tijuana and at 1257 m water depth (32º29.5′N, 117º28.3′W), for trace metal content in two operationally-defined fractions, HCl and pyrite. Our results indicate a transference of Cu > Ni > Zn >> Hg and Ag from the HCl to the pyrite fraction. Sediments have degrees of pyritization (DOP) that averaged 7.2 ± 4.9%, with a maximum value of 18.5%. Average degrees of trace metal pyritization (DTMP) ranged from 6.2 ± 2.1% to 83 ± 18% for Mn and Hg, respectively, although maximum values for some metals were close to 100%. This transference is apparently a function of the solubility products of metal sulfides and the relative abundances of metals in the HCl fraction, as suggested by the significant correlation (p < 0.001) observed between these two parameters and the DTMP of a number of trace metals. A similar correlation was obtained from published data of two cores collected in the Gulf of Mexico. https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/456trace metalspyritesedimentdegree of trace metal pyritizationBaja California
spellingShingle C Nava-López
MA Huerta-Díaz
Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexico
Ciencias Marinas
trace metals
pyrite
sediment
degree of trace metal pyritization
Baja California
title Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexico
title_full Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexico
title_fullStr Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexico
title_full_unstemmed Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexico
title_short Degree of trace metal pyritization in sediments from the Pacific coast of baja california, mexico
title_sort degree of trace metal pyritization in sediments from the pacific coast of baja california mexico
topic trace metals
pyrite
sediment
degree of trace metal pyritization
Baja California
url https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/456
work_keys_str_mv AT cnavalopez degreeoftracemetalpyritizationinsedimentsfromthepacificcoastofbajacaliforniamexico
AT mahuertadiaz degreeoftracemetalpyritizationinsedimentsfromthepacificcoastofbajacaliforniamexico