Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylate
The title compound, C28H34N2O8S2, was synthesized as part of a project to develop synthetic routes to analogues of sporidesmins, a class of secondary metabolite produced by the filamentous fungi Chaetomium and Pithomyces sp. The complete molecule is generated by crystallographic inversion symmetry:...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809022211 |
| _version_ | 1818792039457751040 |
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| author | Nathan W. Polaske Gary S. Nichol Bogdan Olenyuk |
| author_facet | Nathan W. Polaske Gary S. Nichol Bogdan Olenyuk |
| author_sort | Nathan W. Polaske |
| collection | DOAJ |
| description | The title compound, C28H34N2O8S2, was synthesized as part of a project to develop synthetic routes to analogues of sporidesmins, a class of secondary metabolite produced by the filamentous fungi Chaetomium and Pithomyces sp. The complete molecule is generated by crystallographic inversion symmetry: the methoxy group is essentially coplanar with the benzene ring to which it is bonded, a mean plane fitted through the non-H atoms of the aromatic ring and the methoxy group having an r.m.s. deviation of 0.0140 Å. Similarly, the ester group is also essentially planar (r.m.s. deviation of a plane fitted through all non-H atoms is 0.0101 Å). There is only one independent C—H...O interaction, which links together adjacent molecules into a two-dimensional sheet in the bc plane. |
| first_indexed | 2024-12-18T15:20:54Z |
| format | Article |
| id | doaj.art-d483f87398f04f9d9f2043e3e06f360f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:20:54Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d483f87398f04f9d9f2043e3e06f360f2022-12-21T21:03:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657o1583o158410.1107/S1600536809022211Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylateNathan W. PolaskeGary S. NicholBogdan OlenyukThe title compound, C28H34N2O8S2, was synthesized as part of a project to develop synthetic routes to analogues of sporidesmins, a class of secondary metabolite produced by the filamentous fungi Chaetomium and Pithomyces sp. The complete molecule is generated by crystallographic inversion symmetry: the methoxy group is essentially coplanar with the benzene ring to which it is bonded, a mean plane fitted through the non-H atoms of the aromatic ring and the methoxy group having an r.m.s. deviation of 0.0140 Å. Similarly, the ester group is also essentially planar (r.m.s. deviation of a plane fitted through all non-H atoms is 0.0101 Å). There is only one independent C—H...O interaction, which links together adjacent molecules into a two-dimensional sheet in the bc plane.http://scripts.iucr.org/cgi-bin/paper?S1600536809022211 |
| spellingShingle | Nathan W. Polaske Gary S. Nichol Bogdan Olenyuk Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylate Acta Crystallographica Section E |
| title | Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylate |
| title_full | Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylate |
| title_fullStr | Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylate |
| title_full_unstemmed | Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylate |
| title_short | Diethyl trans-2,5-bis(4-methoxybenzylsulfanyl)-1,4-dimethyl-3,6-dioxopiperazine-2,5-carboxylate |
| title_sort | diethyl trans 2 5 bis 4 methoxybenzylsulfanyl 1 4 dimethyl 3 6 dioxopiperazine 2 5 carboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809022211 |
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