Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate
The asymmetric unit of the title compound, [Co2(C10H2O4S3)2(C12H8N2)4]·2C3H7NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octahedral environment and is ligated to four N atoms of two 1,10-phenanthroline molec...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809011337 |
| _version_ | 1819280047473688576 |
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| author | Ronald E. Noftle Cynthia S. Day Christopher M. MacNeill |
| author_facet | Ronald E. Noftle Cynthia S. Day Christopher M. MacNeill |
| author_sort | Ronald E. Noftle |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Co2(C10H2O4S3)2(C12H8N2)4]·2C3H7NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octahedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylate anions. The anions act as bridges between the CoII centers. |
| first_indexed | 2024-12-24T00:37:35Z |
| format | Article |
| id | doaj.art-d4aa41dda32a41debc44c9c8b82d2a66 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:37:35Z |
| publishDate | 2009-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d4aa41dda32a41debc44c9c8b82d2a662022-12-21T17:24:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m486m48610.1107/S1600536809011337Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvateRonald E. NoftleCynthia S. DayChristopher M. MacNeillThe asymmetric unit of the title compound, [Co2(C10H2O4S3)2(C12H8N2)4]·2C3H7NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octahedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylate anions. The anions act as bridges between the CoII centers.http://scripts.iucr.org/cgi-bin/paper?S1600536809011337 |
| spellingShingle | Ronald E. Noftle Cynthia S. Day Christopher M. MacNeill Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate Acta Crystallographica Section E |
| title | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate |
| title_full | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate |
| title_fullStr | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate |
| title_full_unstemmed | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate |
| title_short | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate |
| title_sort | bis amp 956 dithieno 3 2 b 2 amp 8242 3 amp 8242 d thiophene 2 6 dicarboxylato amp 954 2o2 o6 bis bis 1 10 phenanthroline amp 954 2n n amp 8242 cobalt ii dimethylformamide disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809011337 |
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