Characterization of phthalate internal donor in MgCl2 supported Ziegler-Natta catalyst by solid state 13C NMR

Ziegler-Natta catalyst for propylene polymerization, which TiCl4 and di-alkyl phthalate were supported on MgCl2, was analyzed by solid state 13C NMR. It was confirmed that the spin-lattice relaxation time (“relaxation time” hereafter) of carbonyl group in phthalate was shortened with increasing meas...

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Bibliographische Detailangaben
Hauptverfasser: Masayoshi Saito, Toshiya Uozumi, Masahide Murata, Takuo Kataoka, Riichiro Chujo
Format: Artikel
Sprache:English
Veröffentlicht: Iran Polymer and Petrochemical Institute 2022-07-01
Schriftenreihe:Polyolefins Journal
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Online Zugang:http://poj.ippi.ac.ir/article_1871_eacec30cd5626f46be59eb989bfa45fa.pdf