On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> Crystals
Co-doped Zinc selenide (ZnSe) is a promising material because of a high photoluminescence efficiency and wide spectral range emission in the visible region. In this work, ZnSe and Eu<sup>3+</sup>/Yb<sup>3+</sup> co-doped ZnSe crystals were grown by the chemical vapour transpo...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2022-04-01
|
Series: | Applied Sciences |
Subjects: | |
Online Access: | https://www.mdpi.com/2076-3417/12/9/4248 |
_version_ | 1797505783423827968 |
---|---|
author | Behnaz Abbasgholi-NA Osamah A. Aldaghri Khalid Hassan Ibnouf Nawal Madkhali Humberto Cabrera |
author_facet | Behnaz Abbasgholi-NA Osamah A. Aldaghri Khalid Hassan Ibnouf Nawal Madkhali Humberto Cabrera |
author_sort | Behnaz Abbasgholi-NA |
collection | DOAJ |
description | Co-doped Zinc selenide (ZnSe) is a promising material because of a high photoluminescence efficiency and wide spectral range emission in the visible region. In this work, ZnSe and Eu<sup>3+</sup>/Yb<sup>3+</sup> co-doped ZnSe crystals were grown by the chemical vapour transport method. Photoluminescence and optical measurements revealed the effect of trivalent rare earth Eu<sup>3+</sup>/Yb<sup>3+</sup> ions on the emission of new lines with enhancement intensity. In the photoluminescence spectrum, some sharp and intense lines were observed that allow for the possibility of covering a broad emission range. Moreover, the optical measurement showed a lower bandgap compared to that of pure ZnSe bulk crystal. This material is suitable for developing optoelectronic devices, which can emit light in the visible and near infrared range with an improved emission efficiency and wide tunability. |
first_indexed | 2024-03-10T04:23:15Z |
format | Article |
id | doaj.art-d4c36015b2e142c4b0ac2b796c20ac04 |
institution | Directory Open Access Journal |
issn | 2076-3417 |
language | English |
last_indexed | 2024-03-10T04:23:15Z |
publishDate | 2022-04-01 |
publisher | MDPI AG |
record_format | Article |
series | Applied Sciences |
spelling | doaj.art-d4c36015b2e142c4b0ac2b796c20ac042023-11-23T07:46:25ZengMDPI AGApplied Sciences2076-34172022-04-01129424810.3390/app12094248On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> CrystalsBehnaz Abbasgholi-NA0Osamah A. Aldaghri1Khalid Hassan Ibnouf2Nawal Madkhali3Humberto Cabrera4Optics Lab, STI Unit, The Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, 34151 Trieste, ItalyPhysics Department, College of Sciences, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh 13318, Saudi ArabiaPhysics Department, College of Sciences, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh 13318, Saudi ArabiaPhysics Department, College of Sciences, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh 13318, Saudi ArabiaOptics Lab, STI Unit, The Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, 34151 Trieste, ItalyCo-doped Zinc selenide (ZnSe) is a promising material because of a high photoluminescence efficiency and wide spectral range emission in the visible region. In this work, ZnSe and Eu<sup>3+</sup>/Yb<sup>3+</sup> co-doped ZnSe crystals were grown by the chemical vapour transport method. Photoluminescence and optical measurements revealed the effect of trivalent rare earth Eu<sup>3+</sup>/Yb<sup>3+</sup> ions on the emission of new lines with enhancement intensity. In the photoluminescence spectrum, some sharp and intense lines were observed that allow for the possibility of covering a broad emission range. Moreover, the optical measurement showed a lower bandgap compared to that of pure ZnSe bulk crystal. This material is suitable for developing optoelectronic devices, which can emit light in the visible and near infrared range with an improved emission efficiency and wide tunability.https://www.mdpi.com/2076-3417/12/9/4248ZnSeco-doped ZnSerare earthsEu<sup>3+</sup>/Yb<sup>3+</sup> |
spellingShingle | Behnaz Abbasgholi-NA Osamah A. Aldaghri Khalid Hassan Ibnouf Nawal Madkhali Humberto Cabrera On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> Crystals Applied Sciences ZnSe co-doped ZnSe rare earths Eu<sup>3+</sup>/Yb<sup>3+</sup> |
title | On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> Crystals |
title_full | On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> Crystals |
title_fullStr | On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> Crystals |
title_full_unstemmed | On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> Crystals |
title_short | On the Absorption and Photoluminescence Properties of Pure ZnSe and Co-Doped ZnSe:Eu<sup>3+</sup>/Yb<sup>3+</sup> Crystals |
title_sort | on the absorption and photoluminescence properties of pure znse and co doped znse eu sup 3 sup yb sup 3 sup crystals |
topic | ZnSe co-doped ZnSe rare earths Eu<sup>3+</sup>/Yb<sup>3+</sup> |
url | https://www.mdpi.com/2076-3417/12/9/4248 |
work_keys_str_mv | AT behnazabbasgholina ontheabsorptionandphotoluminescencepropertiesofpureznseandcodopedznseeusup3supybsup3supcrystals AT osamahaaldaghri ontheabsorptionandphotoluminescencepropertiesofpureznseandcodopedznseeusup3supybsup3supcrystals AT khalidhassanibnouf ontheabsorptionandphotoluminescencepropertiesofpureznseandcodopedznseeusup3supybsup3supcrystals AT nawalmadkhali ontheabsorptionandphotoluminescencepropertiesofpureznseandcodopedznseeusup3supybsup3supcrystals AT humbertocabrera ontheabsorptionandphotoluminescencepropertiesofpureznseandcodopedznseeusup3supybsup3supcrystals |