Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plasters

In this study, we investigated the kinetics of extraction from aqueous solutions of Fe3+, Cu2+ and Pb2+ by filter loadings, derived from the steelmaking slags. A formal kinetic approach based on the relationship between the relative deposition rate (α) and time (τ) was used to estimate the mechanism...

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Main Author: A. I. Teran
Format: Article
Language:English
Published: Belarusian National Technical University 2020-01-01
Series:Литьë и металлургия
Subjects:
Online Access:https://lim.bntu.by/jour/article/view/3156
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author A. I. Teran
author_facet A. I. Teran
author_sort A. I. Teran
collection DOAJ
description In this study, we investigated the kinetics of extraction from aqueous solutions of Fe3+, Cu2+ and Pb2+ by filter loadings, derived from the steelmaking slags. A formal kinetic approach based on the relationship between the relative deposition rate (α) and time (τ) was used to estimate the mechanism and kinetic parameters of the deposition process). From the set of equations are selected those that in a given region of the degree of completion of the process gave the minimum value of the variance, that is, described the process in the system at this stage with the maximum probability. Three models that best correspond to real processes are selected. It was found that the deposition process at the initial stage limits the chemical stage of nucleation (formation of crystalline precipitate), then – the reaction at the interface (formation of a continuous layer of reaction products on the surface of the nuclei), and at the final stage – the growth of a continuous layer of reaction products.
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spelling doaj.art-d4c879a9b1f2408d8ce76823f9bc50a22025-03-02T13:30:24ZengBelarusian National Technical UniversityЛитьë и металлургия1683-60652414-04062020-01-0104768010.21122/1683-6065-2019-4-76-803066Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plastersA. I. Teran0Belarusian National Technical UniversityIn this study, we investigated the kinetics of extraction from aqueous solutions of Fe3+, Cu2+ and Pb2+ by filter loadings, derived from the steelmaking slags. A formal kinetic approach based on the relationship between the relative deposition rate (α) and time (τ) was used to estimate the mechanism and kinetic parameters of the deposition process). From the set of equations are selected those that in a given region of the degree of completion of the process gave the minimum value of the variance, that is, described the process in the system at this stage with the maximum probability. Three models that best correspond to real processes are selected. It was found that the deposition process at the initial stage limits the chemical stage of nucleation (formation of crystalline precipitate), then – the reaction at the interface (formation of a continuous layer of reaction products on the surface of the nuclei), and at the final stage – the growth of a continuous layer of reaction products.https://lim.bntu.by/jour/article/view/3156iron (iii)copper(ii)lead (ii)kineticspurification degree.
spellingShingle A. I. Teran
Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plasters
Литьë и металлургия
iron (iii)
copper(ii)
lead (ii)
kinetics
purification degree.
title Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plasters
title_full Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plasters
title_fullStr Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plasters
title_full_unstemmed Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plasters
title_short Kinetics of extraction from water solutions of Fe<sup>3+</sup>, Cu<sup>2+</sup> and Pb<sup>2+</sup> + ions by filter loading, obtained by blinding plasters
title_sort kinetics of extraction from water solutions of fe sup 3 sup cu sup 2 sup and pb sup 2 sup ions by filter loading obtained by blinding plasters
topic iron (iii)
copper(ii)
lead (ii)
kinetics
purification degree.
url https://lim.bntu.by/jour/article/view/3156
work_keys_str_mv AT aiteran kineticsofextractionfromwatersolutionsoffesup3supcusup2supandpbsup2supionsbyfilterloadingobtainedbyblindingplasters