Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry
Products of titanium dissolution in the active state are investigated in fluoride containing 1 M H2SO4 solutions. The novel method of dual dynamic voltammetry, applied to Ti disk/Pt ring rotating ring–disk electrodes, is utilized for the simultaneous detection of different dissolution products. Pot...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Association of Physical Chemists (IAPC)
2018-05-01
|
| Series: | Journal of Electrochemical Science and Engineering |
| Subjects: | |
| Online Access: | http://pub.iapchem.org/ojs/index.php/JESE/article/view/502 |
| _version_ | 1831629603917004800 |
|---|---|
| author | Noémi Kovács Laura Sziráki Soma Vesztergom Gyözö G. Láng |
| author_facet | Noémi Kovács Laura Sziráki Soma Vesztergom Gyözö G. Láng |
| author_sort | Noémi Kovács |
| collection | DOAJ |
| description | Products of titanium dissolution in the active state are investigated in fluoride containing 1 M H2SO4 solutions. The novel method of dual dynamic voltammetry, applied to Ti disk/Pt ring rotating ring–disk electrodes, is utilized for the simultaneous detection of different dissolution products. Potential regions where certain products (primarily, TiIII and H2) are formed are identified by a 3D electrochemical map constructed based on the ring–disk electrode measurements. Besides dissolution in the form of TiIII species and hydrogen evolution, the formation and prompt oxidation of TiII can also be presumed under the applied conditions. |
| first_indexed | 2024-12-19T02:02:25Z |
| format | Article |
| id | doaj.art-d4ce98a54c504e3aba6c35359d924e31 |
| institution | Directory Open Access Journal |
| issn | 1847-9286 |
| language | English |
| last_indexed | 2024-12-19T02:02:25Z |
| publishDate | 2018-05-01 |
| publisher | International Association of Physical Chemists (IAPC) |
| record_format | Article |
| series | Journal of Electrochemical Science and Engineering |
| spelling | doaj.art-d4ce98a54c504e3aba6c35359d924e312022-12-21T20:41:01ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862018-05-018210.5599/jese.502297Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetryNoémi Kovács0Laura Sziráki1Soma Vesztergom2Gyözö G. Láng3Department of Physical Chemistry, Laboratory of Electrochemistry and Electroanalytical Chemistry, Eötvös Loránd UniversityDepartment of Physical Chemistry, Laboratory of Electrochemistry and Electroanalytical Chemistry, Eötvös Loránd UniversityDepartment of Physical Chemistry, Laboratory of Electrochemistry and Electroanalytical Chemistry, Eötvös Loránd UniversityDepartment of Physical Chemistry, Laboratory of Electrochemistry and Electroanalytical Chemistry, Eötvös Loránd UniversityProducts of titanium dissolution in the active state are investigated in fluoride containing 1 M H2SO4 solutions. The novel method of dual dynamic voltammetry, applied to Ti disk/Pt ring rotating ring–disk electrodes, is utilized for the simultaneous detection of different dissolution products. Potential regions where certain products (primarily, TiIII and H2) are formed are identified by a 3D electrochemical map constructed based on the ring–disk electrode measurements. Besides dissolution in the form of TiIII species and hydrogen evolution, the formation and prompt oxidation of TiII can also be presumed under the applied conditions.http://pub.iapchem.org/ojs/index.php/JESE/article/view/502Rotating ring–disk electrodeselectrochemical mapcyclic voltammetrydental implant materialscorrosion |
| spellingShingle | Noémi Kovács Laura Sziráki Soma Vesztergom Gyözö G. Láng Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry Journal of Electrochemical Science and Engineering Rotating ring–disk electrodes electrochemical map cyclic voltammetry dental implant materials corrosion |
| title | Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry |
| title_full | Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry |
| title_fullStr | Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry |
| title_full_unstemmed | Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry |
| title_short | Investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry |
| title_sort | investigating products of titanium dissolution in the presence of fluoride ions with dual dynamic voltammetry |
| topic | Rotating ring–disk electrodes electrochemical map cyclic voltammetry dental implant materials corrosion |
| url | http://pub.iapchem.org/ojs/index.php/JESE/article/view/502 |
| work_keys_str_mv | AT noemikovacs investigatingproductsoftitaniumdissolutioninthepresenceoffluorideionswithdualdynamicvoltammetry AT laurasziraki investigatingproductsoftitaniumdissolutioninthepresenceoffluorideionswithdualdynamicvoltammetry AT somavesztergom investigatingproductsoftitaniumdissolutioninthepresenceoffluorideionswithdualdynamicvoltammetry AT gyozoglang investigatingproductsoftitaniumdissolutioninthepresenceoffluorideionswithdualdynamicvoltammetry |