catena-Poly[[aquabis[2-(3-benzoylphenyl)propanoato-κ2O1,O1′]cadmium(II)]-μ-4,4′-bipyridine-κ2N:N′]
The 4,4′-bipyridine heterocycle in the polymeric title compound, [Cd(C16H13O3)2(C10H8N2)(H2O)]n, links adjacent Cd(II) ions into a chain running along the c axis. The Cd atom, which lies on a twofold rotation axis, is chelated by the carboxylate unit and exists in a seven-coordinate pe...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811001280 |
| Summary: | The 4,4′-bipyridine heterocycle in the polymeric title compound, [Cd(C16H13O3)2(C10H8N2)(H2O)]n, links adjacent Cd(II) ions into a chain running along the c axis. The Cd atom, which lies on a twofold rotation axis, is chelated by the carboxylate unit and exists in a seven-coordinate pentagonal–bipyramidal geometry. The apical sites are occupied by N atoms. The water molecule also lies on the twofold rotation axis. The methyl substituent of the propanoate group is disordered over two positions in a 1:1 ratio. O—H...O hydrogen bonding between water molecules and adjacent carboxylate O atoms is observed. |
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| ISSN: | 1600-5368 |